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Racemisation of 1-arylethylamines with shvo-type organoruthenium catalysts
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Taylor, Paul C., Apps, James Frederick Shuan-Liang, Livingston, Andrew, Parrett, Mark R., Pounder, Ryan J. and Turner, Andy (2014) Racemisation of 1-arylethylamines with shvo-type organoruthenium catalysts. Synlett, Volume 25 (Number 10). pp. 1391-1394. doi:10.1055/s-0033-1341228
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Official URL: http://dx.doi.org/10.1055/s-0033-1341228
Abstract
Variation of the electronic nature of the tetraphenylcyclopentadienone ligand in organoruthenium complexes influences their utility for racemisation of model chiral amines. Our study highlights the need to balance reactivity and selectivity in the design of racemisation catalysts. Electron-poor Shvo-type catalysts are, at first sight, more effective for racemisation, but yield more by-product; electron-rich complexes are less proficient at racemisation, but lead to less by-product.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Journal or Publication Title: | Synlett | ||||
| Publisher: | Georg Thieme Verlag | ||||
| ISSN: | 0936-5214 | ||||
| Official Date: | June 2014 | ||||
| Dates: |
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| Volume: | Volume 25 | ||||
| Number: | Number 10 | ||||
| Page Range: | pp. 1391-1394 | ||||
| DOI: | 10.1055/s-0033-1341228 | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Access rights to Published version: | Restricted or Subscription Access |
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