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Electrochemical “read–write” microscale patterning of boron doped diamond electrodes

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Patten, Hollie V., Hutton, Laura A., Webb, Jennifer R., Newton, Mark E., Unwin, Patrick R. and Macpherson, Julie V. (2014) Electrochemical “read–write” microscale patterning of boron doped diamond electrodes. Chemical Communications, Volume 51 (Number 1). pp. 164-167. doi:10.1039/c4cc07830f

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Official URL: http://dx.doi.org/10.1039/c4cc07830f

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Abstract

Scanning electrochemical cell microscopy is utilised as a read–write pipette-based probe to both electrochemically modify the local surface chemistry of boron doped diamond and “read” the resulting modification, at the micron scale. In this specific application, localised electrochemical oxidation results in conversion of the H-terminated surface to –O, electrochemically visualised by monitoring the current change for reduction of Ru(NH3)63+. This methodology, in general, provides a platform for read–write analysis of electrodes, opening up new analytical avenues, particularly as the pipette can be viewed as a microfluidic device.

Item Type: Journal Article
Divisions: Faculty of Science > Chemistry
Faculty of Science > Molecular Organisation and Assembly in Cells (MOAC)
Faculty of Science > Physics
Journal or Publication Title: Chemical Communications
Publisher: Royal Society of Chemistry
ISSN: 1359-7345
Official Date: 6 November 2014
Dates:
DateEvent
6 November 2014Published
6 November 2014Accepted
6 October 2014Submitted
Volume: Volume 51
Number: Number 1
Page Range: pp. 164-167
DOI: 10.1039/c4cc07830f
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Open Access

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