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Phosphotungstic acid encapsulated in metal-organic framework as catalysts for carbohydrate dehydration to 5-hydroxymethylfurfural
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Zhang, Yanmei, Degirmenci, Volkan, Li, Can and Hensen, Emiel J. M. (2011) Phosphotungstic acid encapsulated in metal-organic framework as catalysts for carbohydrate dehydration to 5-hydroxymethylfurfural. Chemsuschem, Volume 4 (Number 1). pp. 59-64. doi:10.1002/cssc.201000284 ISSN 1864-5631.
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Official URL: http://dx.doi.org/10.1002/cssc.201000284
Abstract
MIL-101, a chromium-based metal–organic framework, is known for its very large pore size, large surface area and good stability. However, applications of this material in catalysis are still limited. 5-Hydroxymethylfurfural (HMF) has been considered a renewable chemical platform for the production of liquid fuels and fine chemicals. Phosphotungstic acid, H3PW12O40 (PTA), encapsulated in MIL-101 is evaluated as a potential catalyst for the selective dehydration of fructose and glucose to 5-hydroxymethylfurfural. The results demonstrate that PTA/MIL-101 is effective for HMF production from fructose in DMSO and can be reused. This is the first example of the application of a metal–organic framework in carbohydrate dehydration.
Item Type: | Journal Article | ||||
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Divisions: | Faculty of Science, Engineering and Medicine > Engineering > Engineering | ||||
Journal or Publication Title: | Chemsuschem | ||||
Publisher: | Wiley - V C H Verlag GmbH & Co. KGaA | ||||
ISSN: | 1864-5631 | ||||
Official Date: | 17 January 2011 | ||||
Dates: |
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Volume: | Volume 4 | ||||
Number: | Number 1 | ||||
Page Range: | pp. 59-64 | ||||
DOI: | 10.1002/cssc.201000284 | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access |
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