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Glucose activation by transient Cr2+ dimers
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Pidko, Evgeny A., Degirmenci, Volkan, Santen, R. A. van and Hensen, Emiel J. M. (2010) Glucose activation by transient Cr2+ dimers. Angewandte Chemie International Edition, Volume 49 (Number 14). pp. 2530-2534. doi:10.1002/anie.201000250 ISSN 1433-7851.
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Official URL: http://dx.doi.org/10.1002/anie.201000250
Abstract
Cat waiting in the wings: The transient formation of Cr2+ dimers through coordination to a second molecule of the catalyst promotes the isomerization of glucose to fructose and explains the unique ability of CrCl2 to catalyze the dehydration of glucose to 5-hydroxymethylfurfural (HMF) in ionic-liquid media. The active-site environment during the rate-controlling step resembles that in hexose isomerase enzymes.
Item Type: | Journal Article | ||||
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Divisions: | Faculty of Science, Engineering and Medicine > Engineering > Engineering | ||||
Journal or Publication Title: | Angewandte Chemie International Edition | ||||
Publisher: | Wiley - V C H Verlag GmbH & Co. KGaA | ||||
ISSN: | 1433-7851 | ||||
Official Date: | 29 March 2010 | ||||
Dates: |
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Volume: | Volume 49 | ||||
Number: | Number 14 | ||||
Page Range: | pp. 2530-2534 | ||||
DOI: | 10.1002/anie.201000250 | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access |
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