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Functional degradable polymers by Xanthate-mediated polymerization
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Hedir, Guillaume, Bell, Craig A., Ieong, Nga Sze, Chapman, Emma, Collins, Ian R., O’Reilly, Rachel K. and Dove, Andrew P. (2014) Functional degradable polymers by Xanthate-mediated polymerization. Macromolecules, Volume 47 (Number 9). pp. 2847-2852. doi:10.1021/ma500428e ISSN 0024-9297 .
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Official URL: http://dx.doi.org/10.1021/ma500428e
Abstract
Herein we report the first example of the controlled synthesis of linear and hyperbranched copolymers of 2-methylene-1,3-dioxepane (MDO) with functional vinyl monomers to deliver a range of functional, degradable polymers by reversible deactivation radical polymerization. The copolymerization was able to be tuned to vary the incorporation of degradable segments to create degradable materials with predictable molar mass, low dispersity values while also featuring side-chain functionality. The formation of nanoparticles by the addition of divinyladipate to form degradable hyperbranched copolymers was proven by DLS and TEM analyses.
| Item Type: | Journal Article | ||||||||
|---|---|---|---|---|---|---|---|---|---|
| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||||||
| Journal or Publication Title: | Macromolecules | ||||||||
| Publisher: | American Chemical Society | ||||||||
| ISSN: | 0024-9297 | ||||||||
| Official Date: | 13 May 2014 | ||||||||
| Dates: |
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| Volume: | Volume 47 | ||||||||
| Number: | Number 9 | ||||||||
| Page Range: | pp. 2847-2852 | ||||||||
| DOI: | 10.1021/ma500428e | ||||||||
| Status: | Peer Reviewed | ||||||||
| Publication Status: | Published | ||||||||
| Access rights to Published version: | Restricted or Subscription Access | ||||||||
| Adapted As: |
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