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Synthesis of star-shaped metallo-polymeric chromophores by atom transfer radical polymerization
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UNSPECIFIED (2005) Synthesis of star-shaped metallo-polymeric chromophores by atom transfer radical polymerization. In: International Symposium on Molecular Materials and Organometallics, Univ Rennes 1, Rennes, FRANCE, MAY 12-14, 2004. Published in: COMPTES RENDUS CHIMIE, 8 (8). pp. 1298-1307. doi:10.1016/j.crci.2004.11.034 ISSN 1631-0748.
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Official URL: http://dx.doi.org/10.1016/j.crci.2004.11.034
Abstract
The synthesis of bromoester-functionalized dialkylaminostyryl-2,2'-bipyridyl ligands and of the corresponding tris[dialkylaminostyryl-2,2'-bipyridine] metal(II) complexes are reported (M = Fe, Ru, Zn). These complexes are used as multifunctional metallo-initiators for the atom transfer radical polymerization (ATRP) of methyl methacrylate. The resulting new star-shaped polymers combine the optical (UV-visible and luminescence) properties of the monomers with good processability, which allow to build high optical quality thin films by the spin-coating technique. (c) 2005 Academie des sciences. Published by Elsevier SAS. All rights reserved.
Item Type: | Conference Item (UNSPECIFIED) | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | COMPTES RENDUS CHIMIE | ||||
Publisher: | EDITIONS SCIENTIFIQUES MEDICALES ELSEVIER | ||||
ISSN: | 1631-0748 | ||||
Official Date: | August 2005 | ||||
Dates: |
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Volume: | 8 | ||||
Number: | 8 | ||||
Number of Pages: | 10 | ||||
Page Range: | pp. 1298-1307 | ||||
DOI: | 10.1016/j.crci.2004.11.034 | ||||
Publication Status: | Published | ||||
Title of Event: | International Symposium on Molecular Materials and Organometallics | ||||
Location of Event: | Univ Rennes 1, Rennes, FRANCE | ||||
Date(s) of Event: | MAY 12-14, 2004 |
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