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"Tethered" Ru(II) catalysts for asymmetric transfer hydrogenation of ketones
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UNSPECIFIED (2005) "Tethered" Ru(II) catalysts for asymmetric transfer hydrogenation of ketones. JOURNAL OF ORGANIC CHEMISTRY, 70 (8). pp. 3188-3197. doi:10.1021/jo050032a ISSN 0022-3263.
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Official URL: http://dx.doi.org/10.1021/jo050032a
Abstract
Stereochemically well-defined ruthenium(II) catalysts have been applied to the asymmetric transfer hydrogenation of a series of ketones. In one case, statistical experimental design was employed to optimize the enantiomeric excess of the product. In the case of the TsDPEN-based systems, the replacement of trans-1,2-diphenyl substitution with cis-, or deletion of one of the phenyl groups, results in significant deterioration of the enantiomeric excess. A new method is described for the synthesis of tethered amino alcohol-containing catalysts.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | JOURNAL OF ORGANIC CHEMISTRY | ||||
Publisher: | AMER CHEMICAL SOC | ||||
ISSN: | 0022-3263 | ||||
Official Date: | 15 April 2005 | ||||
Dates: |
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Volume: | 70 | ||||
Number: | 8 | ||||
Number of Pages: | 10 | ||||
Page Range: | pp. 3188-3197 | ||||
DOI: | 10.1021/jo050032a | ||||
Publication Status: | Published |
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