
The Library
Tethered Ru(II) catalysts containing a Ru–I bond
Tools
Jolley, Katherine E., Clarkson, Guy J. and Wills, Martin (2015) Tethered Ru(II) catalysts containing a Ru–I bond. Journal of Organometallic Chemistry, 776 . pp. 157-162. doi:10.1016/j.jorganchem.2014.10.033 ISSN 0022-328X.
|
PDF
WRAP_9574780-ch-250915-jorganchem-d-14-00478_corrected_161014_for_wrap (1).pdf - Accepted Version - Requires a PDF viewer. Download (1074Kb) | Preview |
|
|
PDF
WRAP-supporting-information-Wills-2015.pdf - Supplemental Material - Requires a PDF viewer. Download (1145Kb) | Preview |
Official URL: http://dx.doi.org/10.1016/j.jorganchem.2014.10.033
Abstract
Two new iodide-containing derivatives of the widely-adopted arene/Ru(II)/TsDPEN catalysts have been prepared and fully characterised, including through X-ray crystallography. They have been evaluated as catalysts for the asymmetric reduction of acetophenone under both transfer (ATH) and pressure hydrogenation (AH) conditions. The iodide-containing complexes are equally efficient in the ATH reaction, but less active in the AH reaction compared to the chloride derivatives.
Item Type: | Journal Article | ||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|
Subjects: | Q Science > QD Chemistry | ||||||||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||||||||
Library of Congress Subject Headings (LCSH): | Ruthenium catalysts | ||||||||||
Journal or Publication Title: | Journal of Organometallic Chemistry | ||||||||||
Publisher: | Elsevier S.A. | ||||||||||
ISSN: | 0022-328X | ||||||||||
Official Date: | 14 January 2015 | ||||||||||
Dates: |
|
||||||||||
Volume: | 776 | ||||||||||
Number of Pages: | 6 | ||||||||||
Page Range: | pp. 157-162 | ||||||||||
DOI: | 10.1016/j.jorganchem.2014.10.033 | ||||||||||
Status: | Peer Reviewed | ||||||||||
Publication Status: | Published | ||||||||||
Access rights to Published version: | Restricted or Subscription Access | ||||||||||
Date of first compliant deposit: | 31 December 2015 | ||||||||||
Date of first compliant Open Access: | 31 December 2015 | ||||||||||
Funder: | Engineering and Physical Sciences Research Council (EPSRC), Birmingham Science City, Advantage West Midlands (AWM), European Regional Development Fund (ERDF) |
Request changes or add full text files to a record
Repository staff actions (login required)
![]() |
View Item |
Downloads
Downloads per month over past year