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Tethered Ru(II) catalysts containing a Ru–I bond
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Jolley, Katherine E., Clarkson, Guy J. and Wills, Martin (2015) Tethered Ru(II) catalysts containing a Ru–I bond. Journal of Organometallic Chemistry, 776 . pp. 157-162. doi:10.1016/j.jorganchem.2014.10.033 ISSN 0022-328X.
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Official URL: http://dx.doi.org/10.1016/j.jorganchem.2014.10.033
Abstract
Two new iodide-containing derivatives of the widely-adopted arene/Ru(II)/TsDPEN catalysts have been prepared and fully characterised, including through X-ray crystallography. They have been evaluated as catalysts for the asymmetric reduction of acetophenone under both transfer (ATH) and pressure hydrogenation (AH) conditions. The iodide-containing complexes are equally efficient in the ATH reaction, but less active in the AH reaction compared to the chloride derivatives.
| Item Type: | Journal Article | ||||||||||
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| Subjects: | Q Science > QD Chemistry | ||||||||||
| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||||||||
| Library of Congress Subject Headings (LCSH): | Ruthenium catalysts | ||||||||||
| Journal or Publication Title: | Journal of Organometallic Chemistry | ||||||||||
| Publisher: | Elsevier S.A. | ||||||||||
| ISSN: | 0022-328X | ||||||||||
| Official Date: | 14 January 2015 | ||||||||||
| Dates: |
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| Volume: | 776 | ||||||||||
| Number of Pages: | 6 | ||||||||||
| Page Range: | pp. 157-162 | ||||||||||
| DOI: | 10.1016/j.jorganchem.2014.10.033 | ||||||||||
| Status: | Peer Reviewed | ||||||||||
| Publication Status: | Published | ||||||||||
| Access rights to Published version: | Restricted or Subscription Access | ||||||||||
| Date of first compliant deposit: | 31 December 2015 | ||||||||||
| Date of first compliant Open Access: | 31 December 2015 | ||||||||||
| Funder: | Engineering and Physical Sciences Research Council (EPSRC), Birmingham Science City, Advantage West Midlands (AWM), European Regional Development Fund (ERDF) |
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