Jolley, Katherine E., Clarkson, Guy J. and Wills, Martin (2015) Tethered Ru(II) catalysts containing a Ru–I bond. Journal of Organometallic Chemistry, 776 . pp. 157-162. doi:10.1016/j.jorganchem.2014.10.033

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Abstract

Two new iodide-containing derivatives of the widely-adopted arene/Ru(II)/TsDPEN catalysts have been prepared and fully characterised, including through X-ray crystallography. They have been evaluated as catalysts for the asymmetric reduction of acetophenone under both transfer (ATH) and pressure hydrogenation (AH) conditions. The iodide-containing complexes are equally efficient in the ATH reaction, but less active in the AH reaction compared to the chloride derivatives.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH):	Ruthenium catalysts
Journal or Publication Title:	Journal of Organometallic Chemistry
Publisher:	Elsevier S.A.
ISSN:	0022-328X
Official Date:	14 January 2015
Dates:	Date Event 14 January 2015 Published 5 November 2014 Available 23 October 2014 Accepted 5 August 2014 Submitted
Date of first compliant deposit:	31 December 2015
Volume:	776
Number of Pages:	6
Page Range:	pp. 157-162
DOI:	10.1016/j.jorganchem.2014.10.033
Status:	Peer Reviewed
Publication Status:	Published
Access rights to Published version:	Restricted or Subscription Access
Funder:	Engineering and Physical Sciences Research Council (EPSRC), Birmingham Science City, Advantage West Midlands (AWM), European Regional Development Fund (ERDF)

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