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Direct formation of tethered Ru(II) catalysts using arene exchange
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Soni, Rina, Jolley, Katherine E., Clarkson, Guy J. and Wills, Martin (2013) Direct formation of tethered Ru(II) catalysts using arene exchange. Organic Letters, 15 (19). pp. 5110-5113. doi:10.1021/ol4024979 ISSN 1523-7060.
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Official URL: http://dx.doi.org/10.1021/ol4024979
Abstract
An ‘arene exchange’ approach has been successfully applied for the first time to the synthesis of Ru(II)-based ‘tethered’ reduction catalysts directly from their ligands in one step. This provides an alternative method for the formation of known complexes, and a route to a series of novel complexes. The novel complexes are highly active in both asymmetric transfer and pressure hydrogenation of ketones.
Item Type: | Journal Article | ||||||||
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Subjects: | Q Science > QD Chemistry | ||||||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||||||
Library of Congress Subject Headings (LCSH): | Aromatic compounds, Ruthenium catalysts | ||||||||
Journal or Publication Title: | Organic Letters | ||||||||
Publisher: | American Chemical Society | ||||||||
ISSN: | 1523-7060 | ||||||||
Official Date: | 26 September 2013 | ||||||||
Dates: |
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Volume: | 15 | ||||||||
Number: | 19 | ||||||||
Number of Pages: | 4 | ||||||||
Page Range: | pp. 5110-5113 | ||||||||
DOI: | 10.1021/ol4024979 | ||||||||
Status: | Peer Reviewed | ||||||||
Publication Status: | Published | ||||||||
Access rights to Published version: | Open Access (Creative Commons) | ||||||||
Date of first compliant deposit: | 31 December 2015 | ||||||||
Date of first compliant Open Access: | 31 December 2015 | ||||||||
Funder: | Engineering and Physical Sciences Research Council (EPSRC), Leverhulme Trust (LT), Birmingham Science City, Advantage West Midlands (AWM), European Regional Development Fund (ERDF) |
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