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One-step grafting of polymers to graphene oxide
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Thomas, Helen R., Phillips, Daniel J., Wilson, Neil R., Gibson, Matthew I. and Rourke, Jonathan (2015) One-step grafting of polymers to graphene oxide. Polymer Chemistry, 6 (48). pp. 8270-8274. doi:10.1039/c5py01358e ISSN 1759-9954.
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Official URL: http://dx.doi.org/10.1039/C5PY01358E
Abstract
The direct grafting of poly(N-isopropylacrylamide) to the basal plane of graphene oxide has been achieved in a single step: cleavage of the terminal thiocarbonylthio group on RAFT grown poly(N-isopropylacrylamide) reveals a reactive thiol that attacks the epoxides present across the surface of graphene oxide. The new composite material was characterised by a combination of SSNMR, FTIR, Raman, EDX, XPS, TGA and contact angle measurement; it shows enhanced thermal stability and solubility in water.
Item Type: | Journal Article | ||||||||||
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Subjects: | Q Science > QD Chemistry | ||||||||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry Faculty of Science, Engineering and Medicine > Science > Physics |
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Library of Congress Subject Headings (LCSH): | Graft copolymers, Graphene | ||||||||||
Journal or Publication Title: | Polymer Chemistry | ||||||||||
Publisher: | Royal Society of Chemistry | ||||||||||
ISSN: | 1759-9954 | ||||||||||
Official Date: | 28 December 2015 | ||||||||||
Dates: |
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Volume: | 6 | ||||||||||
Number: | 48 | ||||||||||
Number of Pages: | 5 | ||||||||||
Page Range: | pp. 8270-8274 | ||||||||||
DOI: | 10.1039/c5py01358e | ||||||||||
Status: | Peer Reviewed | ||||||||||
Publication Status: | Published | ||||||||||
Access rights to Published version: | Open Access (Creative Commons) | ||||||||||
Date of first compliant deposit: | 8 December 2015 | ||||||||||
Date of first compliant Open Access: | 9 December 2015 | ||||||||||
Funder: | Engineering and Physical Sciences Research Council (EPSRC), University of Warwick, Advantage West Midlands (AWM), European Regional Development Fund (ERDF), European Research Council (ERC) | ||||||||||
Grant number: | 638661 CRYOMAT (ERC) |
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