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N-Functionalised TsDPEN catalysts for asymmetric transfer hydrogenation; synthesis and applications
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Soni, Rina, Hall, Thomas Howard, Morris, David J., Clarkson, Guy J., Owen, Matthew R. and Wills, Martin (2015) N-Functionalised TsDPEN catalysts for asymmetric transfer hydrogenation; synthesis and applications. Tetrahedron Letters, 56 (46). pp. 6397-6401. doi:10.1016/j.tetlet.2015.09.135 ISSN 0040-4039.
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Official URL: http://dx.doi.org/10.1016/j.tetlet.2015.09.135
Abstract
A series of Ru(II)/arene complexes containing N-alkylated derivatives of TsDPEN were prepared and tested in the asymmetric transfer hydrogenation (ATH) of ketones. The results demonstrated that a wide variety of functionality were tolerated on the basic amine of the TsDPEN ligand, without significantly disrupting the ability of the catalyst to catalyse hydrogen transfer reactions.
| Item Type: | Journal Article | ||||||||
|---|---|---|---|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry | ||||||||
| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||||||
| Library of Congress Subject Headings (LCSH): | Hydrogenation, Asymmetric synthesis, Alcohols -- Synthesis, Chemistry, Physical organic chemistry | ||||||||
| Journal or Publication Title: | Tetrahedron Letters | ||||||||
| Publisher: | Elsevier | ||||||||
| ISSN: | 0040-4039 | ||||||||
| Official Date: | 30 September 2015 | ||||||||
| Dates: |
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| Volume: | 56 | ||||||||
| Number: | 46 | ||||||||
| Page Range: | pp. 6397-6401 | ||||||||
| DOI: | 10.1016/j.tetlet.2015.09.135 | ||||||||
| Status: | Peer Reviewed | ||||||||
| Publication Status: | Published | ||||||||
| Access rights to Published version: | Restricted or Subscription Access | ||||||||
| Date of first compliant deposit: | 15 January 2016 | ||||||||
| Date of first compliant Open Access: | 18 November 2016 | ||||||||
| Funder: | Leverhulme Trust (LT), Engineering and Physical Sciences Research Council (EPSRC) | ||||||||
| Grant number: | RPG-374 , EP/F061420/1 |
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