Hauser, Simone A., Prokes, Ivan and Chaplin, Adrian B. (2015) Low-coordinate iridium NHC complexes derived from selective and reversible C–H bond activation of fluoroarenes. Chemical Communications, 51 (21). pp. 4425-4428. doi:10.1039/c5cc00529a

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Abstract

Interaction of the reactive 14 VE {Ir(IBioxMe4)3}+ fragment with fluoroarenes results exclusively in ortho-C–H bond oxidative addition and formation of 16 VE Ir(III) derivatives [Ir(IBioxMe4)3(Ar)H]+ (Ar = 2-C6H4F, 2,3-C6H3F2, 2,4,6-C6H2F3). The C–H bond activation reactions occur under mild conditions and are reversible.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH):	Iridium compounds
Journal or Publication Title:	Chemical Communications
Publisher:	Royal Society of Chemistry
ISSN:	1359-7345
Official Date:	14 March 2015
Dates:	Date Event 14 March 2015 Published 13 February 2015 Available 6 February 2015 Accepted 19 January 2015 Submitted
Volume:	51
Number:	21
Number of Pages:	4
Page Range:	pp. 4425-4428
DOI:	10.1039/c5cc00529a
Status:	Peer Reviewed
Publication Status:	Published
Access rights to Published version:	Restricted or Subscription Access
Funder:	Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung [Swiss National Science Foundation] (SNSF), Royal Society (Great Britain), University of Warwick

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