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Low-coordinate iridium NHC complexes derived from selective and reversible C–H bond activation of fluoroarenes

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Hauser, Simone A., Prokes, Ivan and Chaplin, Adrian B. (2015) Low-coordinate iridium NHC complexes derived from selective and reversible C–H bond activation of fluoroarenes. Chemical Communications, 51 (21). pp. 4425-4428. doi:10.1039/c5cc00529a

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Official URL: http://dx.doi.org/10.1039/C5CC00529A

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Abstract

Interaction of the reactive 14 VE {Ir(IBioxMe4)3}+ fragment with fluoroarenes results exclusively in ortho-C–H bond oxidative addition and formation of 16 VE Ir(III) derivatives [Ir(IBioxMe4)3(Ar)H]+ (Ar = 2-C6H4F, 2,3-C6H3F2, 2,4,6-C6H2F3). The C–H bond activation reactions occur under mild conditions and are reversible.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH): Iridium compounds
Journal or Publication Title: Chemical Communications
Publisher: Royal Society of Chemistry
ISSN: 1359-7345
Official Date: 14 March 2015
Dates:
DateEvent
14 March 2015Published
13 February 2015Available
6 February 2015Accepted
19 January 2015Submitted
Date of first compliant deposit: 10 February 2016
Volume: 51
Number: 21
Number of Pages: 4
Page Range: pp. 4425-4428
DOI: 10.1039/c5cc00529a
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access
Funder: Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung [Swiss National Science Foundation] (SNSF), Royal Society (Great Britain), University of Warwick

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