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Low-coordinate iridium NHC complexes derived from selective and reversible C–H bond activation of fluoroarenes
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Hauser, Simone A., Prokes, Ivan and Chaplin, Adrian B. (2015) Low-coordinate iridium NHC complexes derived from selective and reversible C–H bond activation of fluoroarenes. Chemical Communications, 51 (21). pp. 4425-4428. doi:10.1039/c5cc00529a ISSN 1359-7345.
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Official URL: http://dx.doi.org/10.1039/C5CC00529A
Abstract
Interaction of the reactive 14 VE {Ir(IBioxMe4)3}+ fragment with fluoroarenes results exclusively in ortho-C–H bond oxidative addition and formation of 16 VE Ir(III) derivatives [Ir(IBioxMe4)3(Ar)H]+ (Ar = 2-C6H4F, 2,3-C6H3F2, 2,4,6-C6H2F3). The C–H bond activation reactions occur under mild conditions and are reversible.
Item Type: | Journal Article | ||||||||||
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Subjects: | Q Science > QD Chemistry | ||||||||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||||||||
Library of Congress Subject Headings (LCSH): | Iridium compounds | ||||||||||
Journal or Publication Title: | Chemical Communications | ||||||||||
Publisher: | Royal Society of Chemistry | ||||||||||
ISSN: | 1359-7345 | ||||||||||
Official Date: | 14 March 2015 | ||||||||||
Dates: |
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Volume: | 51 | ||||||||||
Number: | 21 | ||||||||||
Number of Pages: | 4 | ||||||||||
Page Range: | pp. 4425-4428 | ||||||||||
DOI: | 10.1039/c5cc00529a | ||||||||||
Status: | Peer Reviewed | ||||||||||
Publication Status: | Published | ||||||||||
Access rights to Published version: | Restricted or Subscription Access | ||||||||||
Date of first compliant deposit: | 10 February 2016 | ||||||||||
Date of first compliant Open Access: | 10 February 2016 | ||||||||||
Funder: | Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung [Swiss National Science Foundation] (SNSF), Royal Society (Great Britain), University of Warwick |
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