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Iron cyclopentadienone complexes derived from C2-symmetric bis-propargylic alcohols; preparation and applications to catalysis

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Hodgkinson, Roy, Del Grosso, Alessandro, Clarkson, Guy J. and Wills, Martin (2016) Iron cyclopentadienone complexes derived from C2-symmetric bis-propargylic alcohols; preparation and applications to catalysis. Dalton Transactions, 45 . pp. 3992-4005. doi:10.1039/c5dt04610f

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Official URL: http://dx.doi.org/10.1039/C5DT04610F

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Abstract

A series of complexes containing the iron-cyclopentadienone structure were prepared by cyclising bis-propargylic alcohols and their derivatives with iron pentacarbonyl. The resulting complexes were characterised and tested in the catalysis of ketone reduction and alcohol oxidation. The complexes are competent catalysts for ketone reduction and alcohol oxidations.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH): Chemistry, Organic, Organometallic compounds
Journal or Publication Title: Dalton Transactions
Publisher: Royal Society of Chemistry
ISSN: 1477-9226
Official Date: March 2016
Dates:
DateEvent
March 2016Published
28 January 2016Available
26 January 2016Accepted
24 November 2015Submitted
Date of first compliant deposit: 15 February 2016
Volume: 45
Page Range: pp. 3992-4005
DOI: 10.1039/c5dt04610f
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Open Access
Funder: Leverhulme Trust (LT), Engineering and Physical Sciences Research Council (EPSRC)
Grant number: RPG-374, EP/M006670/1

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