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Iron cyclopentadienone complexes derived from C2-symmetric bis-propargylic alcohols; preparation and applications to catalysis
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Hodgkinson, Roy, Del Grosso, Alessandro, Clarkson, Guy J. and Wills, Martin (2016) Iron cyclopentadienone complexes derived from C2-symmetric bis-propargylic alcohols; preparation and applications to catalysis. Dalton Transactions, 45 . pp. 3992-4005. doi:10.1039/c5dt04610f
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Official URL: http://dx.doi.org/10.1039/C5DT04610F
Abstract
A series of complexes containing the iron-cyclopentadienone structure were prepared by cyclising bis-propargylic alcohols and their derivatives with iron pentacarbonyl. The resulting complexes were characterised and tested in the catalysis of ketone reduction and alcohol oxidation. The complexes are competent catalysts for ketone reduction and alcohol oxidations.
| Item Type: | Journal Article | ||||||||||
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| Subjects: | Q Science > QD Chemistry | ||||||||||
| Divisions: | Faculty of Science > Chemistry | ||||||||||
| Library of Congress Subject Headings (LCSH): | Chemistry, Organic, Organometallic compounds | ||||||||||
| Journal or Publication Title: | Dalton Transactions | ||||||||||
| Publisher: | Royal Society of Chemistry | ||||||||||
| ISSN: | 1477-9226 | ||||||||||
| Official Date: | March 2016 | ||||||||||
| Dates: |
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| Date of first compliant deposit: | 15 February 2016 | ||||||||||
| Volume: | 45 | ||||||||||
| Page Range: | pp. 3992-4005 | ||||||||||
| DOI: | 10.1039/c5dt04610f | ||||||||||
| Status: | Peer Reviewed | ||||||||||
| Publication Status: | Published | ||||||||||
| Access rights to Published version: | Open Access | ||||||||||
| Funder: | Leverhulme Trust (LT), Engineering and Physical Sciences Research Council (EPSRC) | ||||||||||
| Grant number: | RPG-374, EP/M006670/1 |
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