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Selecting phthalocyanine polymorphs using local chemical termination variations in copper iodide

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Ramadan, Alexandra J., Hancox, Ian, Huband, Steven, Parkinson, C. R., Bon, Stefan Antonius Franciscus, Walker, Marc, Fearn, Sarah, McConville, C. F., Jones, T. S. (Tim S.) and Rochford, Luke A. (2016) Selecting phthalocyanine polymorphs using local chemical termination variations in copper iodide. The Journal of Physical Chemistry C, 120 (8). pp. 4448-4452. doi:10.1021/acs.jpcc.6b00354

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Official URL: http://dx.doi.org/10.1021/acs.jpcc.6b00354

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Abstract

Copper(I) iodide (CuI) thin films are employed as a structural templating layer for the growth of metal-free phthalocyanine (H2Pc) thin films. Structural polymorphs are observed in X-ray diffraction patterns when microcrystalline CuI films exhibiting copper and iodine terminated grains are used. Each polymorph is nucleated from a single termination, and distinctive crystallite morphologies are observed for each.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Chemistry
Faculty of Science > Physics
Library of Congress Subject Headings (LCSH): Phthalocyanines, Cuprous iodide
Journal or Publication Title: The Journal of Physical Chemistry C
Publisher: American Chemical Society
ISSN: 1932-7447
Official Date: 6 March 2016
Dates:
DateEvent
6 March 2016Published
5 February 2016Accepted
2 January 2016Submitted
Volume: 120
Number: 8
Number of Pages: 5
Page Range: pp. 4448-4452
DOI: 10.1021/acs.jpcc.6b00354
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Open Access
Funder: Engineering and Physical Sciences Research Council (EPSRC), Science City Research Alliance, Advantage West Midlands (AWM), European Regional Development Fund (ERDF)
Grant number: EP/H021388/1 (EPSRC)

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