Asymmetric hydrogenation of ketones using a ruthenium(II) catalyst containing BINOL-derived monodonor phosphorus-donor ligands
UNSPECIFIED. (2004) Asymmetric hydrogenation of ketones using a ruthenium(II) catalyst containing BINOL-derived monodonor phosphorus-donor ligands. ORGANIC LETTERS, 6 (22). pp. 4105-4107. ISSN 1523-7060Full text not available from this repository.
Official URL: http://dx.doi.org/10.1021/ol0481840
A series of ruthenium(II) complexes containing BINOL-based monodonor phosphorus ligands have been prepared and applied to the asymmetric catalysis of the hydrogenation of aryl/alkyl ketones. The best ligands for this application are those which contain an aromatic groups with either a methoxide or bromide on the ortho position. Using these ligands, alcohols with ee's of up to 99% are formed.
|Item Type:||Journal Article|
|Subjects:||Q Science > QD Chemistry|
|Journal or Publication Title:||ORGANIC LETTERS|
|Publisher:||AMER CHEMICAL SOC|
|Date:||28 October 2004|
|Number of Pages:||3|
|Page Range:||pp. 4105-4107|
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