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Asymmetric hydrogenation of ketones using a ruthenium(II) catalyst containing BINOL-derived monodonor phosphorus-donor ligands
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UNSPECIFIED. (2004) Asymmetric hydrogenation of ketones using a ruthenium(II) catalyst containing BINOL-derived monodonor phosphorus-donor ligands. ORGANIC LETTERS, 6 (22). pp. 4105-4107. ISSN 1523-7060
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Official URL: http://dx.doi.org/10.1021/ol0481840
Abstract
A series of ruthenium(II) complexes containing BINOL-based monodonor phosphorus ligands have been prepared and applied to the asymmetric catalysis of the hydrogenation of aryl/alkyl ketones. The best ligands for this application are those which contain an aromatic groups with either a methoxide or bromide on the ortho position. Using these ligands, alcohols with ee's of up to 99% are formed.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | ORGANIC LETTERS |
| Publisher: | AMER CHEMICAL SOC |
| ISSN: | 1523-7060 |
| Date: | 28 October 2004 |
| Volume: | 6 |
| Number: | 22 |
| Number of Pages: | 3 |
| Page Range: | pp. 4105-4107 |
| Identification Number: | 10.1021/ol0481840 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/7823 |
Data sourced from Thomson Reuters' Web of Knowledge
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