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Degradable precision polynorbornenes via ring-opening metathesis polymerization
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Moatsou, Dafni, Nagarkar, Amit, Kilbinger, Andreas F. M. and O'Reilly, Rachel K. (2016) Degradable precision polynorbornenes via ring-opening metathesis polymerization. Journal of Polymer Science Part A: Polymer Chemistry, 54 (9). pp. 1236-1242. doi:10.1002/pola.27964 ISSN 0887-624X.
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Official URL: http://dx.doi.org/10.1002/pola.27964
Abstract
In an attempt to introduce monomer sequence control in a growing polynorbornene via ring-opening metathesis polymerization, we employ dioxepins to efficiently determine the location of the monomers on the macromolecule backbone. Owing to the acid-labile acetal group, dioxepins allow scission of the polymer at the point of the dioxepin insertion and thus provide an indirect way to determine the monomer location. Additionally, dioxepins are used as spacers in the synthesis of multiblock polynorbornenes that are readily cleavable to afford the individual polynorbornene blocks.
Item Type: | Journal Article | ||||||||||
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Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||||||||
Journal or Publication Title: | Journal of Polymer Science Part A: Polymer Chemistry | ||||||||||
Publisher: | John Wiley & Sons Ltd. | ||||||||||
ISSN: | 0887-624X | ||||||||||
Official Date: | 1 May 2016 | ||||||||||
Dates: |
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Volume: | 54 | ||||||||||
Number: | 9 | ||||||||||
Page Range: | pp. 1236-1242 | ||||||||||
DOI: | 10.1002/pola.27964 | ||||||||||
Status: | Peer Reviewed | ||||||||||
Publication Status: | Published | ||||||||||
Access rights to Published version: | Restricted or Subscription Access | ||||||||||
Description: | epub ahead of print |
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