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Precision polymers : a kinetic approach for functional poly(norbornenes)
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Moatsou, Dafni, Hansell, Claire F. and O'Reilly, Rachel K. (2014) Precision polymers : a kinetic approach for functional poly(norbornenes). Chemical Science, 5 (6). pp. 2246-2250. c4sc00752b. doi:10.1039/c4sc00752b ISSN 2041-6520.
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Official URL: http://dx.doi.org/10.1039/C4SC00752B
Abstract
The potential control over monomer sequence in the ring-opening metathesis polymerization of functional norbornenes is explored based on the difference in reactivity of endo and exo isomers. This kinetic approach allows the rapid consumption of the exo-norbornene and insertion onto the growing poly(norbornene) chain within a narrow region of the overall polymer chain, whilst maintaining a homogeneous backbone. We herein demonstrate that this can be achieved using a range of functional monomers easily derived from commercially available precursors while their polymerization is carried out in a controlled manner.
Item Type: | Journal Article | ||||||||||
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Subjects: | Q Science > QD Chemistry | ||||||||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||||||||
Library of Congress Subject Headings (LCSH): | Ring-opening polymerization | ||||||||||
Journal or Publication Title: | Chemical Science | ||||||||||
Publisher: | Royal Society of Chemistry | ||||||||||
ISSN: | 2041-6520 | ||||||||||
Official Date: | 1 June 2014 | ||||||||||
Dates: |
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Volume: | 5 | ||||||||||
Number: | 6 | ||||||||||
Number of Pages: | 5 | ||||||||||
Page Range: | pp. 2246-2250 | ||||||||||
Article Number: | c4sc00752b | ||||||||||
DOI: | 10.1039/c4sc00752b | ||||||||||
Status: | Peer Reviewed | ||||||||||
Publication Status: | Published | ||||||||||
Access rights to Published version: | Open Access (Creative Commons) | ||||||||||
Funder: | Engineering and Physical Sciences Research Council (EPSRC), Birmingham Science City, Advantage West Midlands (AWM), European Regional Development Fund (ERDF) |
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