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Exploiting the tetrazine–norbornene reaction for single polymer chain collapse
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Hansell, Claire F., Lu, Annhelen, Patterson, Joseph P. and O'Reilly, Rachel K. (2014) Exploiting the tetrazine–norbornene reaction for single polymer chain collapse. Nanoscale, 6 (8). p. 4102. doi:10.1039/c3nr06706h ISSN 2040-3364.
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Official URL: http://dx.doi.org/10.1039/C3NR06706H
Abstract
Single chain polymer nanoparticles (SCNPs) have been formed using polystyrenes decorated with pendent norbornenes and a bifunctional tetrazine crosslinker. Characterisation by size exclusion chromatography and 1H NMR gives evidence for the formation of SCNPs by the tetrazine–norbornene reaction, whilst light scattering, neutron scattering, transmission electron microscopy and atomic force microscopy show that discrete well-defined nanoparticles are formed and their size in solution calculated.
Item Type: | Journal Article | ||||||||||
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Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||||||||
Journal or Publication Title: | Nanoscale | ||||||||||
Publisher: | Royal Society of Chemistry | ||||||||||
ISSN: | 2040-3364 | ||||||||||
Official Date: | 21 April 2014 | ||||||||||
Dates: |
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Volume: | 6 | ||||||||||
Number: | 8 | ||||||||||
Page Range: | p. 4102 | ||||||||||
DOI: | 10.1039/c3nr06706h | ||||||||||
Status: | Peer Reviewed | ||||||||||
Publication Status: | Published | ||||||||||
Access rights to Published version: | Restricted or Subscription Access |
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