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Freezing properties of alkenyl succinic anhydrides derived from linear isomerized olefins
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Sellars, Phillip, Lue, Leo, Burns, Iain S. and Work, D. Neil (2016) Freezing properties of alkenyl succinic anhydrides derived from linear isomerized olefins. Industrial & Engineering Chemistry Research, 55 (8). pp. 2287-2292. doi:10.1021/acs.iecr.5b04769 ISSN 0888-5885.
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Official URL: http://dx.doi.org/10.1021/acs.iecr.5b04769
Abstract
Alkenyl succinic anhydrides are important specialty chemicals that are used in the paper, oilfield, and fuel additives industries. In this paper we investigate the link between the physical properties of alkenyl succinic anhydrides and the identities of their linear alkyl olefin precursors. We describe a straightforward GC analysis of olefin isomer distributions and show that these correlate well with the freezing temperatures of the subsequent alkenyl succinic anhydride products. This allows the identification of olefin isomer profiles that are required to give the desired physical properties in the alkenyl succinic anhydrides; it also provides a method to predict the freezing temperatures of alkenyl succinic anhydrides synthesized from a particular supply of olefin.
Item Type: | Journal Article | ||||||
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Divisions: | Faculty of Science, Engineering and Medicine > Engineering > WMG (Formerly the Warwick Manufacturing Group) | ||||||
Journal or Publication Title: | Industrial & Engineering Chemistry Research | ||||||
Publisher: | American Chemical Society | ||||||
ISSN: | 0888-5885 | ||||||
Official Date: | 8 February 2016 | ||||||
Dates: |
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Volume: | 55 | ||||||
Number: | 8 | ||||||
Page Range: | pp. 2287-2292 | ||||||
DOI: | 10.1021/acs.iecr.5b04769 | ||||||
Status: | Peer Reviewed | ||||||
Publication Status: | Published | ||||||
Access rights to Published version: | Restricted or Subscription Access |
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