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Ba4Ru3O10.2(OH)1.8 : a new member of the layered hexagonal perovskite family crystallised from water
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Hiley, Craig I., Lees, Martin R., Hammond, David L., Kashtiban, Reza J., Sloan, Jeremy, Smith, Ronald I. and Walton, Richard I. (2016) Ba4Ru3O10.2(OH)1.8 : a new member of the layered hexagonal perovskite family crystallised from water. Chemical Communications, 52 (38). pp. 6375-6378. doi:10.1039/c6cc02121b ISSN 1359-7345.
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Official URL: http://dx.doi.org/10.1039/C6CC02121B
Abstract
A new barium ruthenium oxyhydroxide Ba4Ru3O10.2(OH)1.8 crystallises under hydrothermal conditions at 200 °C: powder neutron diffraction data show it adopts an 8H hexagonal perovskite structure with a new stacking sequence, while high resolution electron microscopy reveals regions of ordered layers of vacant Ru sites, and magnetometry shows antiferromagnetism with TN = 200(5) K.
Item Type: | Journal Article | ||||||||
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Subjects: | Q Science > QD Chemistry | ||||||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry Faculty of Science, Engineering and Medicine > Science > Physics |
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Library of Congress Subject Headings (LCSH): | Perovskite | ||||||||
Journal or Publication Title: | Chemical Communications | ||||||||
Publisher: | Royal Society of Chemistry | ||||||||
ISSN: | 1359-7345 | ||||||||
Official Date: | 7 April 2016 | ||||||||
Dates: |
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Volume: | 52 | ||||||||
Number: | 38 | ||||||||
Number of Pages: | 4 | ||||||||
Page Range: | pp. 6375-6378 | ||||||||
DOI: | 10.1039/c6cc02121b | ||||||||
Status: | Peer Reviewed | ||||||||
Publication Status: | Published | ||||||||
Access rights to Published version: | Open Access (Creative Commons) | ||||||||
Date of first compliant deposit: | 8 July 2016 | ||||||||
Date of first compliant Open Access: | 11 July 2016 | ||||||||
Funder: | Engineering and Physical Sciences Research Council (EPSRC) |
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