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Surface patterning of polyacrylamide gel using scanning electrochemical cell microscopy (SECCM)
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Oseland, Elizabeth E., Ayres, Zoë J., Basile, Andrew, Haddleton, David M., Wilson, Paul and Unwin, Patrick R. (2016) Surface patterning of polyacrylamide gel using scanning electrochemical cell microscopy (SECCM). Chemical Communications, 52 (64). pp. 9929-9932. doi:10.1039/C6CC05153G ISSN 1359-7345.
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WRAP-surface-patterning-polyacrylamide-gel-selctrochemical-microscopy-Wilson-2016.pdf - Accepted Version - Requires a PDF viewer. Download (1032Kb) | Preview |
Official URL: http://dx.doi.org/10.1039/C6CC05153G
Abstract
Scanning electrochemical cell microscopy is introduced as a new tool for the synthesis and deposition of polymers on SAM-functionalised Au surfaces. The deposition of poly(N-hydroxyethyl acrylamide) is shown to be enhanced through the electrochemical generation of activating Cu(I)Cl/Me6TREN catalyst. Initiation of the polymerisation reaction is most likely due to in situ generation of reactive oxygen species following oxygen reduction.
Item Type: | Journal Article | |||||||||||||||
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Subjects: | Q Science > QD Chemistry | |||||||||||||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | |||||||||||||||
Library of Congress Subject Headings (LCSH): | Polymers -- Synthesis, Gold, Polymerization | |||||||||||||||
Journal or Publication Title: | Chemical Communications | |||||||||||||||
Publisher: | Royal Society of Chemistry | |||||||||||||||
ISSN: | 1359-7345 | |||||||||||||||
Official Date: | 19 July 2016 | |||||||||||||||
Dates: |
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Volume: | 52 | |||||||||||||||
Number: | 64 | |||||||||||||||
Page Range: | pp. 9929-9932 | |||||||||||||||
DOI: | 10.1039/C6CC05153G | |||||||||||||||
Status: | Peer Reviewed | |||||||||||||||
Publication Status: | Published | |||||||||||||||
Access rights to Published version: | Restricted or Subscription Access | |||||||||||||||
Date of first compliant deposit: | 9 October 2018 | |||||||||||||||
Date of first compliant Open Access: | 9 October 2018 | |||||||||||||||
RIOXX Funder/Project Grant: |
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