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The redox chemistry of SbF6- ion
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UNSPECIFIED (2004) The redox chemistry of SbF6- ion. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (16). pp. 3273-3276. doi:10.1002/ejic.200400150 ISSN 1434-1948.
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Official URL: http://dx.doi.org/10.1002/ejic.200400150
Abstract
Chemical analysis of Sb in coordination compounds requires quantitative reduction of Sb-v in the form of SbF6- (and its related fluoro-hydroxy species) to Sb-III. This process, although thermodynamically favoured, appears to be kinetically hindered. The experimentally observed stabilisation of SbF6- towards reduction, as happens when the associated metal counterion is complexed by XeF2 (generally regarded as being an oxidizing agent), is also discussed. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | ||||
Publisher: | WILEY-V C H VERLAG GMBH | ||||
ISSN: | 1434-1948 | ||||
Official Date: | 20 August 2004 | ||||
Dates: |
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Number: | 16 | ||||
Number of Pages: | 4 | ||||
Page Range: | pp. 3273-3276 | ||||
DOI: | 10.1002/ejic.200400150 | ||||
Publication Status: | Published |
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