The redox chemistry of SbF6- ion
UNSPECIFIED. (2004) The redox chemistry of SbF6- ion. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (16). pp. 3273-3276. ISSN 1434-1948Full text not available from this repository.
Official URL: http://dx.doi.org/10.1002/ejic.200400150
Chemical analysis of Sb in coordination compounds requires quantitative reduction of Sb-v in the form of SbF6- (and its related fluoro-hydroxy species) to Sb-III. This process, although thermodynamically favoured, appears to be kinetically hindered. The experimentally observed stabilisation of SbF6- towards reduction, as happens when the associated metal counterion is complexed by XeF2 (generally regarded as being an oxidizing agent), is also discussed. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.
|Item Type:||Journal Article|
|Subjects:||Q Science > QD Chemistry|
|Journal or Publication Title:||EUROPEAN JOURNAL OF INORGANIC CHEMISTRY|
|Publisher:||WILEY-V C H VERLAG GMBH|
|Official Date:||20 August 2004|
|Number of Pages:||4|
|Page Range:||pp. 3273-3276|
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