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A perovskite oxide with high conductivities in both air and reducing atmosphere for use as electrode for solid oxide fuel cells
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Lan, Rong, Cowin, Peter I., Sengodan, Sivaprakash and Tao, Shanwen (2016) A perovskite oxide with high conductivities in both air and reducing atmosphere for use as electrode for solid oxide fuel cells. Scientific Reports, 6 . 31839. doi:10.1038/srep31839 ISSN 2045-2322.
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Official URL: http://dx.doi.org/10.1038/srep31839
Abstract
Electrode materials which exhibit high conductivities in both oxidising and reducing atmospheres are in high demand for solid oxide fuel cells (SOFCs) and solid oxide electrolytic cells (SOECs). In this paper, we investigated Cu-doped SrFe0.9Nb0.1O3−δ finding that the primitive perovskite oxide SrFe0.8Cu0.1Nb0.1O3−δ (SFCN) exhibits a conductivity of 63 Scm−1and 60 Scm−1 at 415 °C in air and 5%H2/Ar respectively. It is believed that the high conductivity in 5%H2/Ar is related to the exsolved Fe (or FeCu alloy) on exposure to a reducing atmosphere. To the best of our knowledge, the conductivity of SrFe0.8Cu0.1Nb0.1O3−δ in a reducing atmosphere is the highest of all reported oxides which also exhibit a high conductivity in air. Fuel cell performance using SrFe0.8Cu0.1Nb0.1O3−δ as the anode, (Y2O3)0.08(ZrO2)0.92 as the electrolyte and La0.8Sr0.2FeO3−δ as the cathode achieved a power density of 423 mWcm−2 at 700 °C indicating that SFCN is a promising anode for SOFCs.
| Item Type: | Journal Article | ||||||||
|---|---|---|---|---|---|---|---|---|---|
| Subjects: | T Technology > TK Electrical engineering. Electronics Nuclear engineering | ||||||||
| Divisions: | Faculty of Science, Engineering and Medicine > Engineering > Engineering | ||||||||
| Library of Congress Subject Headings (LCSH): | Fuel cells , Electrodes, Electric conductors, Perovskite | ||||||||
| Journal or Publication Title: | Scientific Reports | ||||||||
| Publisher: | Nature Publishing Group | ||||||||
| ISSN: | 2045-2322 | ||||||||
| Official Date: | 22 August 2016 | ||||||||
| Dates: |
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| Volume: | 6 | ||||||||
| Article Number: | 31839 | ||||||||
| DOI: | 10.1038/srep31839 | ||||||||
| Status: | Peer Reviewed | ||||||||
| Publication Status: | Published | ||||||||
| Access rights to Published version: | Open Access (Creative Commons) | ||||||||
| Date of first compliant deposit: | 31 August 2016 | ||||||||
| Date of first compliant Open Access: | 31 August 2016 | ||||||||
| Funder: | Engineering and Physical Sciences Research Council (EPSRC) | ||||||||
| Grant number: | EP/K021036/2, EP/I037016/1, EP/G030995/1 | ||||||||
| Adapted As: |
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