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Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4-x)H2O (M = V4+, x = 0; M = Ga3+, x = 1) : co-existence of ordered and disordered quantum spins in the V4+ system
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Manson, Jamie L., Schlueter, John A., Garrett, Kerry E. , Goddard, Paul, Lancaster, Tom, Möller, Johannes S., Blundell, Stephen J., Steele, Andrew J., Franke, Isabel, Pratt, Francis L., Singleton, John, Bendix, Jesper, Lapidus, Saul H., Uhlarz, Marc, Ayala-Valenzuela, Oscar, McDonald, Ross D., Gurak, Mary and Baines, Christopher (2016) Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4-x)H2O (M = V4+, x = 0; M = Ga3+, x = 1) : co-existence of ordered and disordered quantum spins in the V4+ system. Chemical Communications, 52 (85). pp. 12653-12656. doi:10.1039/C6CC05873F ISSN 1359-7345.
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Official URL: http://dx.doi.org/10.1039/C6CC05873F
Abstract
The title compounds are bimetallic MOFs containing [Cu(pyz)2]2+ square lattices linked by MF6n- octahedra. In each, only the Cu2+ spins exhibit long-range magnetic order below 3.5 K (M = V4+) and 2.6 K (M = Ga3+). The V4+ spins remain disordered down to 0.5 K.
Item Type: | Journal Article | ||||||||||||||||||
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Subjects: | Q Science > QC Physics | ||||||||||||||||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Physics | ||||||||||||||||||
Library of Congress Subject Headings (LCSH): | Magnetic materials, Ligands, Metal ions | ||||||||||||||||||
Journal or Publication Title: | Chemical Communications | ||||||||||||||||||
Publisher: | Royal Society of Chemistry | ||||||||||||||||||
ISSN: | 1359-7345 | ||||||||||||||||||
Official Date: | 2016 | ||||||||||||||||||
Dates: |
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Volume: | 52 | ||||||||||||||||||
Number: | 85 | ||||||||||||||||||
Page Range: | pp. 12653-12656 | ||||||||||||||||||
DOI: | 10.1039/C6CC05873F | ||||||||||||||||||
Status: | Peer Reviewed | ||||||||||||||||||
Publication Status: | Published | ||||||||||||||||||
Access rights to Published version: | Restricted or Subscription Access | ||||||||||||||||||
Date of first compliant deposit: | 29 September 2016 | ||||||||||||||||||
Date of first compliant Open Access: | 27 September 2017 | ||||||||||||||||||
RIOXX Funder/Project Grant: |
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