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Data for Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4-x)H2O (M = V4+, x = 0; M = Ga3+, x = 1) : co-existence of ordered and disordered quantum spins in the V4+ system

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Manson, Jamie L., Schlueter, J. A., Garrett, Kerry E., Goddard, Paul, Lancaster, Tom, Möller, Johannes S., Blundell, Stephen, Steele, Andrew J., Franke, Isabel, Pratt, Francis L., Singleton, John, Bendix, Jesper, Lapidus, Saul H., Uhlarz, M., Ayala-Valenzuela, Oscar, McDonald, Ross D., Gurak, Mary and Baines, Christopher (2016) Data for Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4-x)H2O (M = V4+, x = 0; M = Ga3+, x = 1) : co-existence of ordered and disordered quantum spins in the V4+ system. [Dataset]

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Abstract

The title compounds are bimetallic MOFs containing [Cu(pyz)2]2+ square lattices linked by MF6n- octahedra. In each, only the Cu2+ spins exhibit long-range magnetic order below 3.5 K (M = V4+) and 2.6 K (M = Ga3+). The V4+ spins remain disordered down to 0.5 K.

Item Type: Dataset
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science, Engineering and Medicine > Science > Physics
Type of Data: Zip file
Library of Congress Subject Headings (LCSH): Magnetic materials, Ligands, Metal ions
Publisher: Department of Physics, University of Warwick
Official Date: December 2016
Dates:
DateEvent
December 2016Accepted
Status: Not Peer Reviewed
Publication Status: Published
Media of Output (format): Text
Access rights to Published version: Open Access
Description:

(H3O)x[Cu(MF6)(pyrazine)2]·(4 − x)H2O Compound 1: M = V4+, x = 0 Compound 2: M = Ga3+, x = 1

file1 compound 1 magnetization (arb. units) vs magnetic field (tesla) taken at T = 0.5 kelvin see Figure 2(b)

file 2 compound 1magnetic susceptibility (emu) vs temperature taken at B = 0.1 tesla mass = 46.3 mg see Figure 2(a)

file 3 compound 2 magnetization (arb. units) vs magnetic field (tesla) taken at T = 0.5 kelvin see Figure 2(b)

file musr_1.dat Compound 1 muSR precession frequency versus temperature (using columns 4 and 9). See Figure 4

file musr_2.dat Compound 2 muSR Gaussian relaxation rate versus temperature (using columns 4 and 7). See Figure 4

RIOXX Funder/Project Grant:
Project/Grant IDRIOXX Funder NameFunder ID
DMR-1306158National Science Foundationhttp://dx.doi.org/10.13039/100000001
DE-AC02-06CH11357U.S. Department of Energyhttp://dx.doi.org/10.13039/100000015
UNSPECIFIED[EPSRC] Engineering and Physical Sciences Research Councilhttp://dx.doi.org/10.13039/501100000266
UNSPECIFIEDForschungszentrum Dresden-Rossendorfhttp://viaf.org/viaf/130865286
UNSPECIFIEDScience and Technology Facilities Councilhttp://dx.doi.org/10.13039/501100000271
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