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Optically generated hyperpolarization for sensitivity enhancement in solution-state NMR spectroscopy
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Dale, Matthew W. and Wedge, Christopher (2016) Optically generated hyperpolarization for sensitivity enhancement in solution-state NMR spectroscopy. Chemical Communications, 52 (90). pp. 13221-13224. doi:10.1039/C6CC06651H
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Official URL: http://dx.doi.org/10.1039/C6CC06651H
Abstract
We show that optical excitation of radical triplet pair systems can produce a fourfold NMR signal enhancement in solution, without the need for microwave pumping. Development of optical hyperpolarization methods will significantly impact all NMR user groups by boosting sensitivity and reducing signal averaging times.
| Item Type: | Journal Article | ||||||||||
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| Subjects: | Q Science > QD Chemistry T Technology > TA Engineering (General). Civil engineering (General) |
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| Divisions: | Faculty of Science > Physics | ||||||||||
| Library of Congress Subject Headings (LCSH): | Nuclear magnetic resonance spectroscopy, Chemistry, Biochemistry , Materials science | ||||||||||
| Journal or Publication Title: | Chemical Communications | ||||||||||
| Publisher: | Royal Society of Chemistry | ||||||||||
| ISSN: | 1359-7345 | ||||||||||
| Official Date: | 21 November 2016 | ||||||||||
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| Date of first compliant deposit: | 4 October 2016 | ||||||||||
| Volume: | 52 | ||||||||||
| Number: | 90 | ||||||||||
| Page Range: | pp. 13221-13224 | ||||||||||
| DOI: | 10.1039/C6CC06651H | ||||||||||
| Status: | Peer Reviewed | ||||||||||
| Publication Status: | Published | ||||||||||
| Access rights to Published version: | Restricted or Subscription Access | ||||||||||
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