The Library
Optically generated hyperpolarization for sensitivity enhancement in solution-state NMR spectroscopy
Tools
Tools
Tools
Dale, Matthew W. and Wedge, Christopher (2016) Optically generated hyperpolarization for sensitivity enhancement in solution-state NMR spectroscopy. Chemical Communications, 52 (90). pp. 13221-13224. doi:10.1039/C6CC06651H
|
PDF
WRAP_c6cc06651h.pdf - Published Version - Requires a PDF viewer. Available under License Creative Commons Attribution. Download (2064Kb) | Preview |
|
![[img]](http://wrap.warwick.ac.uk/style/images/fileicons/application_pdf.png) |
PDF
WRAP_Wedge_AcceptedManuscript.pdf - Accepted Version Embargoed item. Restricted access to Repository staff only - Requires a PDF viewer. Download (1195Kb) |
Official URL: http://dx.doi.org/10.1039/C6CC06651H
Abstract
We show that optical excitation of radical triplet pair systems can produce a fourfold NMR signal enhancement in solution, without the need for microwave pumping. Development of optical hyperpolarization methods will significantly impact all NMR user groups by boosting sensitivity and reducing signal averaging times.
| Item Type: | Journal Article | ||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry T Technology > TA Engineering (General). Civil engineering (General) |
||||||||||
| Divisions: | Faculty of Science, Engineering and Medicine > Science > Physics | ||||||||||
| Library of Congress Subject Headings (LCSH): | Nuclear magnetic resonance spectroscopy, Chemistry, Biochemistry , Materials science | ||||||||||
| Journal or Publication Title: | Chemical Communications | ||||||||||
| Publisher: | Royal Society of Chemistry | ||||||||||
| ISSN: | 1359-7345 | ||||||||||
| Official Date: | 21 November 2016 | ||||||||||
| Dates: |
|
||||||||||
| Volume: | 52 | ||||||||||
| Number: | 90 | ||||||||||
| Page Range: | pp. 13221-13224 | ||||||||||
| DOI: | 10.1039/C6CC06651H | ||||||||||
| Status: | Peer Reviewed | ||||||||||
| Publication Status: | Published | ||||||||||
| Access rights to Published version: | Restricted or Subscription Access | ||||||||||
| RIOXX Funder/Project Grant: |
|
||||||||||
| Related URLs: |
Request changes or add full text files to a record
Repository staff actions (login required)
 |
View Item |
