Ferroelectric glass ceramics based on the bismuth germanate system
UNSPECIFIED (2004) Ferroelectric glass ceramics based on the bismuth germanate system. In: 7th International Symposium on Crystallisation in Glasses and Liquids, Univ Sheffield, Sheffield, ENGLAND, JUL 06-09, 2003. Published in: PHYSICS AND CHEMISTRY OF GLASSES, 45 (2). pp. 79-82.Full text not available from this repository.
Glasses have been formed from the BiO1.5-GeO2-BO1.5 and BiO1.5-GeO2-TeO2 systems and glass ceramics produced by controlled devitrification. The ferroelectric phase, orthorhombic Bi2GeO5, crystallises in all of the borate glasses studied and is the dominant phase for the 60BiO(1.5):20GeO(2):20BO(1.5) composition. The glass forming region of the BiO1.5-GeO2-TeO2 system is quite narrow and, whilst Bi2GeO5 could be formed along with Bi4TeO8 at low TeO2 contents, this was replaced by Bi-4(GeO4)(3) at higher concentrations. On increasing the temperature, the Bi2GeO5 devitrification in the borate containing glass ceramics changes from spherulitic to surface crystallisation which can be used to produce oriented growth. Such Bi2GeO5 glass ceramics are ferroelectric at room temperature with T-C=407degreesC The polarisation P-s = 0(.)14 C/m(2) is comparable with that of BaTiO3 ceramic but a high voltage is required for poling. The preferred orientation of the surface crystallisation in this glass ceramic is perpendicular to the Bi2GeO5 (311) planes but a-axis orientation may be preferable, in order to enhance the electrical properties.
|Item Type:||Conference Item (UNSPECIFIED)|
|Subjects:||Q Science > QD Chemistry
T Technology > TP Chemical technology
|Journal or Publication Title:||PHYSICS AND CHEMISTRY OF GLASSES|
|Publisher:||SOC GLASS TECHNOLOGY|
|Number of Pages:||4|
|Page Range:||pp. 79-82|
|Title of Event:||7th International Symposium on Crystallisation in Glasses and Liquids|
|Location of Event:||Univ Sheffield, Sheffield, ENGLAND|
|Date(s) of Event:||JUL 06-09, 2003|
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