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Nanoscale structure and morphology of thin films of poly(2-chloroxylylene) synthesized by the CVD method on different liquids

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Porzio, William, Scavia, Guido, Arnautov, Sergey, Conzatti, Lucia, Charmet, Jérôme, Laux, Edith, Keppner, Herbert, Zerbi, Giuseppe, Brambilla, Luigi and Bolognesi, Alberto (2011) Nanoscale structure and morphology of thin films of poly(2-chloroxylylene) synthesized by the CVD method on different liquids. European Polymer Journal, 47 (9). pp. 1725-1735. doi:10.1016/j.eurpolymj.2011.06.016

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Official URL: http://dx.doi.org/10.1016/j.eurpolymj.2011.06.016

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Abstract

Poly(2-chloroxylylene) (PCX) thin films are obtained on the surface of liquids with different density and surface tension values. Morphology of these films is different showing increasing roughness and hydrophobicity in correlation with aforementioned physical parameters. A detailed study by means of vibrational spectroscopy, XRD and TEM of the structure of PCX at the interface with the liquid is reported. The results here obtained prove the possibility to tailor the surface of thin solid films of PCX changing the liquid substrate thus addressing the surface functionalities.

Item Type: Journal Article
Divisions: Faculty of Science > WMG (Formerly the Warwick Manufacturing Group)
Journal or Publication Title: European Polymer Journal
Publisher: Pergamon
ISSN: 0014-3057
Official Date: September 2011
Dates:
DateEvent
September 2011Published
8 July 2011Available
23 June 2011Accepted
Volume: 47
Number: 9
Page Range: pp. 1725-1735
DOI: 10.1016/j.eurpolymj.2011.06.016
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access

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