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Nanoscale structure and morphology of thin films of poly(2-chloroxylylene) synthesized by the CVD method on different liquids
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Porzio, William, Scavia, Guido, Arnautov, Sergey, Conzatti, Lucia, Charmet, Jérôme, Laux, Edith, Keppner, Herbert, Zerbi, Giuseppe, Brambilla, Luigi and Bolognesi, Alberto (2011) Nanoscale structure and morphology of thin films of poly(2-chloroxylylene) synthesized by the CVD method on different liquids. European Polymer Journal, 47 (9). pp. 1725-1735. doi:10.1016/j.eurpolymj.2011.06.016
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Official URL: http://dx.doi.org/10.1016/j.eurpolymj.2011.06.016
Abstract
Poly(2-chloroxylylene) (PCX) thin films are obtained on the surface of liquids with different density and surface tension values. Morphology of these films is different showing increasing roughness and hydrophobicity in correlation with aforementioned physical parameters. A detailed study by means of vibrational spectroscopy, XRD and TEM of the structure of PCX at the interface with the liquid is reported. The results here obtained prove the possibility to tailor the surface of thin solid films of PCX changing the liquid substrate thus addressing the surface functionalities.
| Item Type: | Journal Article | ||||||||
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| Divisions: | Faculty of Science > WMG (Formerly the Warwick Manufacturing Group) | ||||||||
| Journal or Publication Title: | European Polymer Journal | ||||||||
| Publisher: | Pergamon | ||||||||
| ISSN: | 0014-3057 | ||||||||
| Official Date: | September 2011 | ||||||||
| Dates: |
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| Volume: | 47 | ||||||||
| Number: | 9 | ||||||||
| Page Range: | pp. 1725-1735 | ||||||||
| DOI: | 10.1016/j.eurpolymj.2011.06.016 | ||||||||
| Status: | Peer Reviewed | ||||||||
| Publication Status: | Published | ||||||||
| Access rights to Published version: | Restricted or Subscription Access |
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