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Local structure determination of NH2 on Si(111)-(7X7)

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UNSPECIFIED. (2004) Local structure determination of NH2 on Si(111)-(7X7). PHYSICAL REVIEW B, 69 (12). -. ISSN 1098-0121

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Official URL: http://dx.doi.org/10.1103/PhysRevB.69.125340

Abstract

N 1s scanned-energy mode photoelectron diffraction has been used to determine the local adsorption geometry of adsorbed NH2 species on Si(111) (7 X 7) resulting from reaction with NH3 at room temperature. The results show that NH2 is adsorbed (almost) exclusively atop Si surface rest atoms with a Si-N bond length of 1.71 +/- 0.02 Angstrom and very little modification of the geometry of the Si atoms in the layer below. Any coadsorbed NH on the surface is either of low relative coverage or is also adsorbed in local atop sites. There is evidence that a small fraction (8 +/- 7 %) of the NHx species may occupy sites atop Si surface adatoms.

Item Type: Journal Article
Subjects: Q Science > QC Physics
Journal or Publication Title: PHYSICAL REVIEW B
Publisher: AMERICAN PHYSICAL SOC
ISSN: 1098-0121
Date: March 2004
Volume: 69
Number: 12
Number of Pages: 9
Page Range: -
Identification Number: 10.1103/PhysRevB.69.125340
Publication Status: Published
URI: http://wrap.warwick.ac.uk/id/eprint/8430

Data sourced from Thomson Reuters' Web of Knowledge

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