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Synthesis of polymeric microcapsules by interfacial-suspension cationic photopolymerisation of divinyl ether monomer in aqueous suspension
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Benedetti, M., Congdon, Thomas R., Bassett, S. P., Alauhdin, M., Howdle, S. M., Haddleton, David M., Pisano, R., Sangermano, M. and Schiller, Tara L. (2017) Synthesis of polymeric microcapsules by interfacial-suspension cationic photopolymerisation of divinyl ether monomer in aqueous suspension. Polymer Chemistry, 8 (6). 972-975 . doi:10.1039/C6PY01782G ISSN 1759-9954.
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WRAP_1374859-wmg-310117-cationic_emulsion_polymerization_revised_v6.pdf - Accepted Version - Requires a PDF viewer. Download (679Kb) | Preview |
Official URL: http://dx.doi.org/10.1039/C6PY01782G
Abstract
Polymeric microcapusles have been synthesised with a markedly more hydrophillic monomer than previously reported, triethylene glycol divinyl ether, using cationic photopolymerisation in an aqueous environment. Characterisation by NMR and SEM show that the particles are formed with low dispersity with a size of approximately 1 μm in spite of the expected inhibition in aqueous conditions. Furthermore, supercritical carbon dioxide has been used to generate silver nanoparticles which distribute throughout the shell of the microcapsules further illustrating the structure of these capsules with characterisation by TEM and SAXS.
| Item Type: | Journal Article | ||||||||||
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| Subjects: | Q Science > QD Chemistry | ||||||||||
| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||||||||
| Library of Congress Subject Headings (LCSH): | Polymers, Capsules (Pharmacy), Polymers in medicine | ||||||||||
| Journal or Publication Title: | Polymer Chemistry | ||||||||||
| Publisher: | Royal Society of Chemistry | ||||||||||
| ISSN: | 1759-9954 | ||||||||||
| Official Date: | 14 February 2017 | ||||||||||
| Dates: |
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| Volume: | 8 | ||||||||||
| Number: | 6 | ||||||||||
| Page Range: | 972-975 | ||||||||||
| DOI: | 10.1039/C6PY01782G | ||||||||||
| Status: | Peer Reviewed | ||||||||||
| Publication Status: | Published | ||||||||||
| Access rights to Published version: | Restricted or Subscription Access | ||||||||||
| Date of first compliant deposit: | 6 February 2017 | ||||||||||
| Date of first compliant Open Access: | 6 January 2018 | ||||||||||
| Adapted As: |
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