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Complexation and proton transfer by hydroxamic acids in model inhibited metallohydrolases: formation of metal hydroxamate trimers
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UNSPECIFIED. (2004) Complexation and proton transfer by hydroxamic acids in model inhibited metallohydrolases: formation of metal hydroxamate trimers. INORGANIC CHEMISTRY COMMUNICATIONS, 7 (4). pp. 495-498. ISSN 1387-7003
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Official URL: http://dx.doi.org/10.1016/j.inoche.2003.12.038
Abstract
Reaction between the dimeric metal complexes, [M-2(mu-OAcF)(2) (OAcF)(2) (mu-H2O)(tmen)(2)], M = Co(II), Ni(II), and aceto- and benzohydroxamic acids (AHA, BHA) gives the novel trimeric complexes, [M-3(mu-OAcF)(4)(mu-RA)(2)(tmen)(2)], M=Co(II), Ni(II); RA = AA, BA, in which each hydroxamate bridges two metal centres via its deprotonated hydroxyl and the carbonyl oxygen bonds one metal centre only together with the doubly protonated salt [(tmen).2H][OAcF](2). In contrast, self-assembly from M(OAcF)(2).4H(2)O, tmen and RHA gives the dibridged hydroxamate dimers [M-2(mu-OAcF)(mu-RA)(2)(tmen)(2)] [OAcF]. (C) 2004 Elsevier B.V. All rights reserved.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | INORGANIC CHEMISTRY COMMUNICATIONS |
| Publisher: | ELSEVIER SCIENCE BV |
| ISSN: | 1387-7003 |
| Date: | April 2004 |
| Volume: | 7 |
| Number: | 4 |
| Number of Pages: | 4 |
| Page Range: | pp. 495-498 |
| Identification Number: | 10.1016/j.inoche.2003.12.038 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/8577 |
Data sourced from Thomson Reuters' Web of Knowledge
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