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Film formation of non-planar phthalocyanines on copper(i) iodide
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Ramadan, A. J., Fearn, S., Jones, T. S., Heutz, S. and Rochford, Luke A. (2016) Film formation of non-planar phthalocyanines on copper(i) iodide. RSC Advances , 6 (97). pp. 95227-95231. doi:10.1039/C6RA21803B
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Official URL: http://dx.doi.org/10.1039/C6RA21803B
Abstract
Structural templating is frequently used in organic photovoltaic devices to control the properties of the functional layers and therefore improve efficiencies. Modification of the substrate temperatures has also been shown to impact the structure and morphology of phthalocyanine thin films. Here we combine templating by copper iodide and high substrate temperature growth and study its effect on the structure and morphology of two different non-planar phthalocyanines, chloroaluminium (ClAlPc) and vanadyl (VOPc) phthalocyanine. X-ray diffraction, atomic force microscopy and low energy ion scattering show that both the morphology and the structure of the films are starkly different in every case, highlighting the versatility of phthalocyanine film growth.
| Item Type: | Journal Article | ||||||||
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| Subjects: | Q Science > QD Chemistry T Technology > TK Electrical engineering. Electronics Nuclear engineering |
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| Divisions: | Faculty of Science > Chemistry | ||||||||
| Library of Congress Subject Headings (LCSH): | Cuprous iodide , Organic semiconductors, Photovoltaic power systems | ||||||||
| Journal or Publication Title: | RSC Advances | ||||||||
| Publisher: | Royal Society of Chemistry | ||||||||
| ISSN: | 2046-2069 | ||||||||
| Official Date: | 26 September 2016 | ||||||||
| Dates: |
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| Volume: | 6 | ||||||||
| Number: | 97 | ||||||||
| Page Range: | pp. 95227-95231 | ||||||||
| DOI: | 10.1039/C6RA21803B | ||||||||
| Status: | Peer Reviewed | ||||||||
| Publication Status: | Published | ||||||||
| Access rights to Published version: | Open Access | ||||||||
| Funder: | Engineering and Physical Sciences Research Council (EPSRC) | ||||||||
| Grant number: | EP/G037515/1 |
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