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Film formation of non-planar phthalocyanines on copper(i) iodide

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Ramadan, A. J., Fearn, S., Jones, T. S., Heutz, S. and Rochford, Luke A. (2016) Film formation of non-planar phthalocyanines on copper(i) iodide. RSC Advances , 6 (97). pp. 95227-95231. doi:10.1039/C6RA21803B

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Official URL: http://dx.doi.org/10.1039/C6RA21803B

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Abstract

Structural templating is frequently used in organic photovoltaic devices to control the properties of the functional layers and therefore improve efficiencies. Modification of the substrate temperatures has also been shown to impact the structure and morphology of phthalocyanine thin films. Here we combine templating by copper iodide and high substrate temperature growth and study its effect on the structure and morphology of two different non-planar phthalocyanines, chloroaluminium (ClAlPc) and vanadyl (VOPc) phthalocyanine. X-ray diffraction, atomic force microscopy and low energy ion scattering show that both the morphology and the structure of the films are starkly different in every case, highlighting the versatility of phthalocyanine film growth.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
T Technology > TK Electrical engineering. Electronics Nuclear engineering
Divisions: Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH): Cuprous iodide , Organic semiconductors, Photovoltaic power systems
Journal or Publication Title: RSC Advances
Publisher: Royal Society of Chemistry
ISSN: 2046-2069
Official Date: 26 September 2016
Dates:
DateEvent
26 September 2016Published
26 September 2016Available
23 September 2016Accepted
Date of first compliant deposit: 30 March 2017
Volume: 6
Number: 97
Page Range: pp. 95227-95231
DOI: 10.1039/C6RA21803B
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Open Access
Funder: Engineering and Physical Sciences Research Council (EPSRC)
Grant number: EP/G037515/1

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