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UV-light promoted C–H bond activation of benzene and fluorobenzenes by an iridium(i) pincer complex
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Hauser, Simone A., Emerson-King, Jack, Habershon, Scott and Chaplin, Adrian B. (2017) UV-light promoted C–H bond activation of benzene and fluorobenzenes by an iridium(i) pincer complex. Chemical Communications, 53 (26). pp. 3634-3636. doi:10.1039/C6CC09807J ISSN 1359-7345.
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Official URL: http://dx.doi.org/10.1039/C6CC09807J
Abstract
Iridium(I) carbonyl complex [Ir(2,6-(PtBu2CH2)2C6H3)(CO)] undergoes reversible C–H bond activation of benzene and a series of fluorobenzenes on UV irradiation. Exclusive ortho-selectivity is observed in reactions of fluorobenzene and 1,2-difluorobenzene.
Item Type: | Journal Article | ||||||
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Subjects: | Q Science > QD Chemistry | ||||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||||
Library of Congress Subject Headings (LCSH): | Chemistry, Organic, Iridium compounds, Fluorides, Benzene | ||||||
Journal or Publication Title: | Chemical Communications | ||||||
Publisher: | Royal Society of Chemistry | ||||||
ISSN: | 1359-7345 | ||||||
Official Date: | 17 March 2017 | ||||||
Dates: |
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Volume: | 53 | ||||||
Number: | 26 | ||||||
Page Range: | pp. 3634-3636 | ||||||
DOI: | 10.1039/C6CC09807J | ||||||
Status: | Peer Reviewed | ||||||
Publication Status: | Published | ||||||
Access rights to Published version: | Open Access (Creative Commons) | ||||||
Date of first compliant deposit: | 3 May 2017 | ||||||
Date of first compliant Open Access: | 8 May 2017 | ||||||
Funder: | Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung [Swiss National Science Foundation] (SNSF), Engineering and Physical Sciences Research Council (EPSRC), Royal Society (Great Britain), University of Warwick, Advantage West Midlands (AWM), European Regional Development Fund (ERDF) |
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