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Kinetic and mechanistic studies of mono(terpyridine)- to bis(terpyridine)-nickel(II) complex formation reactions involving a range of substituted 2,2 ': 6 ',2 ''-terpyridine ligands: an investigation of pi-stacking interactions in outer-sphere complexes.
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UNSPECIFIED (2003) Kinetic and mechanistic studies of mono(terpyridine)- to bis(terpyridine)-nickel(II) complex formation reactions involving a range of substituted 2,2 ': 6 ',2 ''-terpyridine ligands: an investigation of pi-stacking interactions in outer-sphere complexes. INORGANIC REACTION MECHANISMS, 5 (1). pp. 21-30. ISSN 1028-6624
Full text not available from this repository.Abstract
Using a range of substituted 2,2': 6%2"-terpyridine ligands, the effects of pi-stacking on the rates of formation of bis(terpyridine)nickel(II) complexes have been investigated in 70:30 v/v % methanol:water. Compared with the rates of formation of the mono(terpyridine)nickel(II) complexes, for the bis(terpyridine)nickel(II) complexes at 25degreesC, rate enhancements in the range 11-146 were found. For unsubstituted 2,2':6',2"-terpyridine studied in the same solvent mixture, the rate enhancement at 25degreesC is 11, whereas for 4'-(2-naphthyl)-2,2':6',2"-terpyridine the rate enhancement is 146.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | INORGANIC REACTION MECHANISMS |
| Publisher: | OLD CITY PUBLISHING INC |
| ISSN: | 1028-6624 |
| Date: | 2003 |
| Volume: | 5 |
| Number: | 1 |
| Number of Pages: | 10 |
| Page Range: | pp. 21-30 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/8869 |
Data sourced from Thomson Reuters' Web of Knowledge
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