The Library
A new class of Rh(III) catalyst containing an aminoalcohol tethered to a tetramethylcyclopentadienyl hydrogenation group for asymmetric transfer of ketones
Tools
UNSPECIFIED (2004) A new class of Rh(III) catalyst containing an aminoalcohol tethered to a tetramethylcyclopentadienyl hydrogenation group for asymmetric transfer of ketones. TETRAHEDRON LETTERS, 45 (4). pp. 843-846. doi:10.1016/j.tetlet.2003.11.024 ISSN 0040-4039.
Research output not available from this repository.
Request-a-Copy directly from author or use local Library Get it For Me service.
Official URL: http://dx.doi.org/10.1016/j.tetlet.2003.11.024
Abstract
The synthesis and application to asymmetric reduction of acetophenone, of a novel class of Rh(III) catalyst containing a tether between the cyclopentadienyl group and a homochiral aminoalcohol, is described. The complex is a highly active catalyst for asymmetric ketone reduction, however it appears to be unstable to the extended reaction conditions. The well-defined stereochemical structure of the catalyst offers potential for significant improvement and 'fine tuning' towards specific substrates. (C) 2003 Elsevier Ltd. All rights reserved.
Item Type: | Journal Article | ||||
---|---|---|---|---|---|
Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | TETRAHEDRON LETTERS | ||||
Publisher: | PERGAMON-ELSEVIER SCIENCE LTD | ||||
ISSN: | 0040-4039 | ||||
Official Date: | 19 January 2004 | ||||
Dates: |
|
||||
Volume: | 45 | ||||
Number: | 4 | ||||
Number of Pages: | 4 | ||||
Page Range: | pp. 843-846 | ||||
DOI: | 10.1016/j.tetlet.2003.11.024 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
Request changes or add full text files to a record
Repository staff actions (login required)
View Item |