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A new class of Rh(III) catalyst containing an aminoalcohol tethered to a tetramethylcyclopentadienyl hydrogenation group for asymmetric transfer of ketones
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UNSPECIFIED. (2004) A new class of Rh(III) catalyst containing an aminoalcohol tethered to a tetramethylcyclopentadienyl hydrogenation group for asymmetric transfer of ketones. TETRAHEDRON LETTERS, 45 (4). pp. 843-846. ISSN 0040-4039
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Official URL: http://dx.doi.org/10.1016/j.tetlet.2003.11.024
Abstract
The synthesis and application to asymmetric reduction of acetophenone, of a novel class of Rh(III) catalyst containing a tether between the cyclopentadienyl group and a homochiral aminoalcohol, is described. The complex is a highly active catalyst for asymmetric ketone reduction, however it appears to be unstable to the extended reaction conditions. The well-defined stereochemical structure of the catalyst offers potential for significant improvement and 'fine tuning' towards specific substrates. (C) 2003 Elsevier Ltd. All rights reserved.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | TETRAHEDRON LETTERS |
| Publisher: | PERGAMON-ELSEVIER SCIENCE LTD |
| ISSN: | 0040-4039 |
| Date: | 19 January 2004 |
| Volume: | 45 |
| Number: | 4 |
| Number of Pages: | 4 |
| Page Range: | pp. 843-846 |
| Identification Number: | 10.1016/j.tetlet.2003.11.024 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/8887 |
Data sourced from Thomson Reuters' Web of Knowledge
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