Synthesis and properties of amphiphilic vinyl acetate triblock copolymers prepared by copper mediated living radical polymerisation
UNSPECIFIED (2003) Synthesis and properties of amphiphilic vinyl acetate triblock copolymers prepared by copper mediated living radical polymerisation. EUROPEAN POLYMER JOURNAL, 39 (12). pp. 2243-2252. ISSN 0014-3057Full text not available from this repository.
Official URL: http://dx.doi.org/10.1016/S0014-3057(03)00179-4
Polymerisation of vinyl acetate by conventional free radical polymerisation using a diazo initiator followed by copper mediated living radical polymerisation with a range of monomers was studied. This method led to the synthesis of triblock copolymers. We have thus successfully prepared several new ABA triblock copolymers where B is poly(vinyl acetate) and A is (dimethylamino)ethyl methacrylate (DMAEMA), (polyethylene glycol) methyl ether methacrylate (MeO(PEG)MA) or solketal methacrylate (SMA). The sequential conventional/living radical polymerisation approach provided an efficient route to synthesis of new block copolymers. The properties of these amphiphilic polymers have been subsequently investigated by H-1 NMR, fluorescence spectroscopy, tensiometry and dynamic light scattering to investigate their behaviour as potential surfactants. (C) 2003 Elsevier Ltd. All rights reserved.
|Item Type:||Journal Article|
|Subjects:||Q Science > QD Chemistry|
|Journal or Publication Title:||EUROPEAN POLYMER JOURNAL|
|Publisher:||PERGAMON-ELSEVIER SCIENCE LTD|
|Number of Pages:||10|
|Page Range:||pp. 2243-2252|
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