Cyclometallated nitrogen heterocycles
UNSPECIFIED. (2003) Cyclometallated nitrogen heterocycles. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 688 (1-2). pp. 112-120. ISSN 0022-328XFull text not available from this repository.
Official URL: http://dx.doi.org/10.1016/j.jorganchem.2003.08.038
The cyclometallation of four different classes of nitrogen heterocycle (pyridazine, tetrazines, pyrazines and pyrimidines) by palladium and platinum has been studied. Pyridazines readily form singly and doubly cyclometallated compounds, whilst pyrazines only metallate once. Both tetrazines and pyrimidines readily metallate once and doubly metallated species have been identified in solution. The use of trans-cyclometallating reagents based on benzylamine and Schiff's base ligands was also studied: considerable promise was shown by a benzylamine compound. (C) 2003 Elsevier B.V. All rights reserved.
|Item Type:||Journal Article|
|Subjects:||Q Science > QD Chemistry|
|Journal or Publication Title:||JOURNAL OF ORGANOMETALLIC CHEMISTRY|
|Publisher:||ELSEVIER SCIENCE SA|
|Official Date:||15 December 2003|
|Number of Pages:||9|
|Page Range:||pp. 112-120|
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