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Controlled radical polymerization of alkyl acrylates and styrene using a half-sandwich molybdenum(III) complex containing diazadiene ligands
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UNSPECIFIED (2003) Controlled radical polymerization of alkyl acrylates and styrene using a half-sandwich molybdenum(III) complex containing diazadiene ligands. EUROPEAN POLYMER JOURNAL, 39 (11). pp. 2099-2105. ISSN 0014-3057
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Official URL: http://dx.doi.org/10.1016/S0014-3057(03)00152-6
Abstract
The half-sandwich molybdenum(III) complex CpMoCl2(Pr-i(2)-dad) (Pr-i(2)-dad = Pr-i-N=CH-CH=N-Pr-i) proved to be an effective metal catalyst for the controlled radical polymerization of methyl acrylate, butyl acrylate, and styrene. In conjunction with an alkyl iodide [R-I: CH3CH(COOEt)I] as an initiator and in the presence or absence of Al(O-i-Pr)(3) as a co-catalyst, the molybdenum-based system gave polymers with narrow molecular weight distributions. The in situ addition of styrene to a macroinitiator of poly(methylacrylate) afforded an AB-type block copolymer. (C) 2003 Elsevier Ltd. All rights reserved.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | EUROPEAN POLYMER JOURNAL |
| Publisher: | PERGAMON-ELSEVIER SCIENCE LTD |
| ISSN: | 0014-3057 |
| Date: | November 2003 |
| Volume: | 39 |
| Number: | 11 |
| Number of Pages: | 7 |
| Page Range: | pp. 2099-2105 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/9122 |
Data sourced from Thomson Reuters' Web of Knowledge
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