Controlled radical polymerization of alkyl acrylates and styrene using a half-sandwich molybdenum(III) complex containing diazadiene ligands
UNSPECIFIED (2003) Controlled radical polymerization of alkyl acrylates and styrene using a half-sandwich molybdenum(III) complex containing diazadiene ligands. EUROPEAN POLYMER JOURNAL, 39 (11). pp. 2099-2105. ISSN 0014-3057Full text not available from this repository.
Official URL: http://dx.doi.org/10.1016/S0014-3057(03)00152-6
The half-sandwich molybdenum(III) complex CpMoCl2(Pr-i(2)-dad) (Pr-i(2)-dad = Pr-i-N=CH-CH=N-Pr-i) proved to be an effective metal catalyst for the controlled radical polymerization of methyl acrylate, butyl acrylate, and styrene. In conjunction with an alkyl iodide [R-I: CH3CH(COOEt)I] as an initiator and in the presence or absence of Al(O-i-Pr)(3) as a co-catalyst, the molybdenum-based system gave polymers with narrow molecular weight distributions. The in situ addition of styrene to a macroinitiator of poly(methylacrylate) afforded an AB-type block copolymer. (C) 2003 Elsevier Ltd. All rights reserved.
|Item Type:||Journal Article|
|Subjects:||Q Science > QD Chemistry|
|Journal or Publication Title:||EUROPEAN POLYMER JOURNAL|
|Publisher:||PERGAMON-ELSEVIER SCIENCE LTD|
|Number of Pages:||7|
|Page Range:||pp. 2099-2105|
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