The Library
Controlled radical polymerization of alkyl acrylates and styrene using a half-sandwich molybdenum(III) complex containing diazadiene ligands
Tools
UNSPECIFIED (2003) Controlled radical polymerization of alkyl acrylates and styrene using a half-sandwich molybdenum(III) complex containing diazadiene ligands. EUROPEAN POLYMER JOURNAL, 39 (11). pp. 2099-2105. doi:10.1016/S0014-3057(03)00152-6 ISSN 0014-3057.
Research output not available from this repository.
Request-a-Copy directly from author or use local Library Get it For Me service.
Official URL: http://dx.doi.org/10.1016/S0014-3057(03)00152-6
Abstract
The half-sandwich molybdenum(III) complex CpMoCl2(Pr-i(2)-dad) (Pr-i(2)-dad = Pr-i-N=CH-CH=N-Pr-i) proved to be an effective metal catalyst for the controlled radical polymerization of methyl acrylate, butyl acrylate, and styrene. In conjunction with an alkyl iodide [R-I: CH3CH(COOEt)I] as an initiator and in the presence or absence of Al(O-i-Pr)(3) as a co-catalyst, the molybdenum-based system gave polymers with narrow molecular weight distributions. The in situ addition of styrene to a macroinitiator of poly(methylacrylate) afforded an AB-type block copolymer. (C) 2003 Elsevier Ltd. All rights reserved.
Item Type: | Journal Article | ||||
---|---|---|---|---|---|
Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | EUROPEAN POLYMER JOURNAL | ||||
Publisher: | PERGAMON-ELSEVIER SCIENCE LTD | ||||
ISSN: | 0014-3057 | ||||
Official Date: | November 2003 | ||||
Dates: |
|
||||
Volume: | 39 | ||||
Number: | 11 | ||||
Number of Pages: | 7 | ||||
Page Range: | pp. 2099-2105 | ||||
DOI: | 10.1016/S0014-3057(03)00152-6 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
Request changes or add full text files to a record
Repository staff actions (login required)
View Item |