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Oxygen moment formation and canting in Li2CuO2

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UNSPECIFIED. (2003) Oxygen moment formation and canting in Li2CuO2. PHYSICAL REVIEW B, 68 (14). -. ISSN 1098-0121

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Official URL: http://dx.doi.org/10.1103/PhysRevB.68.144410

Abstract

The possibilities of oxygen moment formation and canting in the quasi-one-dimensional (quasi-1D) cuprate Li2CuO2 are investigated using single-crystal neutron diffraction at 2 K. The observed magnetic intensities could not be explained without the inclusion of a large ordered oxygen moment of 0.11(1)mu(B). Least-squares refinement of the magnetic structure of Li2CuO2 in combination with a spin-density Patterson analysis shows that the magnetization densities of the Cu and O atoms are highly aspherical, forming quasi-1D ribbons of localized Cu and O moments. Magnetic structure refinements and low-field magnetization measurements both suggest that the magnetic structure of Li2CuO2 at 2 K may be canted. A possible model for the canted configuration is proposed.

Item Type: Journal Article
Subjects: Q Science > QC Physics
Journal or Publication Title: PHYSICAL REVIEW B
Publisher: AMERICAN PHYSICAL SOC
ISSN: 1098-0121
Date: 1 October 2003
Volume: 68
Number: 14
Number of Pages: 9
Page Range: -
Identification Number: 10.1103/PhysRevB.68.144410
Publication Status: Published
URI: http://wrap.warwick.ac.uk/id/eprint/9144

Data sourced from Thomson Reuters' Web of Knowledge

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