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Thiol-reactive (co)polymer scaffolds comprising organic arsenical acrylamides
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Footman, Charlotte, de Jongh, Patrick A. J. M., Tanaka, Joji, Peltier, Raoul, Kempe, Kristian, Davis, Thomas P. and Wilson, Paul (2017) Thiol-reactive (co)polymer scaffolds comprising organic arsenical acrylamides. Chemical Communications, 53 (60). pp. 8447-8450. doi:10.1039/c7cc03880a
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WRAP-Thiol-reactive-(co)polymer-scaffolds-comprising-organic-arsenical-acrylamides-Wilson-2017.pdf - Accepted Version - Requires a PDF viewer. Download (892Kb) | Preview |
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Official URL: http://dx.doi.org/10.1039/c7cc03880a
Abstract
Novel, well-defined organic arsenical homopolymers (Đ = 1.10–1.40) have been synthesised via RAFT polymerisation. Copolymerisation of the As-functional monomer with dimethylacrylamide yielded non-toxic polymer scaffolds (Đ ≈ 1.10) that could be manipulated in response to pH and undergo sequential reduction and substitution in the presence of thiols including cysteine and glutathione.
| Item Type: | Journal Article | ||||||||||||||||||||||||
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| Subjects: | Q Science > QD Chemistry | ||||||||||||||||||||||||
| Divisions: | Faculty of Science > Chemistry | ||||||||||||||||||||||||
| Library of Congress Subject Headings (LCSH): | Polymerization, Polymers, Block copolymers, Thiols, Arsenic compounds | ||||||||||||||||||||||||
| Journal or Publication Title: | Chemical Communications | ||||||||||||||||||||||||
| Publisher: | Royal Society of Chemistry | ||||||||||||||||||||||||
| ISSN: | 1359-7345 | ||||||||||||||||||||||||
| Official Date: | 6 July 2017 | ||||||||||||||||||||||||
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| Volume: | 53 | ||||||||||||||||||||||||
| Number: | 60 | ||||||||||||||||||||||||
| Page Range: | pp. 8447-8450 | ||||||||||||||||||||||||
| DOI: | 10.1039/c7cc03880a | ||||||||||||||||||||||||
| Status: | Peer Reviewed | ||||||||||||||||||||||||
| Publication Status: | Published | ||||||||||||||||||||||||
| Access rights to Published version: | Restricted or Subscription Access | ||||||||||||||||||||||||
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