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Reversible surface functionalisation of emulsion-templated porous polymers using dithiophenol maleimide functional macromolecules

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Eissa, Ahmed M., Wilson, Paul, Chen, Chang-Hui, Collins, Jennifer, Walker, Marc, Haddleton, David M. and Cameron, Neil R. (2017) Reversible surface functionalisation of emulsion-templated porous polymers using dithiophenol maleimide functional macromolecules. Chemical Communications, 53 (70). pp. 9789-9792. doi:10.1039/C7CC03811A

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Official URL: http://dx.doi.org/10.1039/C7CC03811A

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Abstract

A new facile and efficient route for the chemical functionalisation of thiol–acrylate polyHIPE materials with responsive macromolecules using the highly emissive dithiomaleimide (DTM) linker is demonstrated. Functionalisation is found to be reversible upon addition of a thiol-containing compound, glutathione, resulting in switchable surface properties including fluorescence and wettability, hence broadening the scope of applications.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Chemistry
Faculty of Science > Engineering
Faculty of Science > Physics
Library of Congress Subject Headings (LCSH): Polymers -- Industrial applications, Emulsion polymerization, Porous materials, Imides, Macromolecules
Journal or Publication Title: Chemical Communications
Publisher: Royal Society of Chemistry
ISSN: 1359-7345
Official Date: 11 September 2017
Dates:
DateEvent
11 September 2017Published
11 August 2017Available
11 August 2017Accepted
Date of first compliant deposit: 8 September 2017
Volume: 53
Number: 70
Number of Pages: 5
Page Range: pp. 9789-9792
DOI: 10.1039/C7CC03811A
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access
Funder: Monash-Warwick Alliance, National Institute for Health Research (Great Britain). Blood and Transplant Unit (NIHR BTRU), NHS Blood and Transplant (NHSBT), Leverhulme Trust (LT)
Grant number: ECF/2015-075 (LT)

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