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Reversible surface functionalisation of emulsion-templated porous polymers using dithiophenol maleimide functional macromolecules
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Eissa, Ahmed M., Wilson, Paul, Chen, Chang-Hui, Collins, Jennifer, Walker, Marc, Haddleton, David M. and Cameron, Neil R. (2017) Reversible surface functionalisation of emulsion-templated porous polymers using dithiophenol maleimide functional macromolecules. Chemical Communications, 53 (70). pp. 9789-9792. doi:10.1039/C7CC03811A ISSN 1359-7345.
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WRAP-reversible-surface-functionalisation-emulsion-templated-porous-polymers-Eissa-2017.pdf - Accepted Version - Requires a PDF viewer. Download (1416Kb) | Preview |
Official URL: http://dx.doi.org/10.1039/C7CC03811A
Abstract
A new facile and efficient route for the chemical functionalisation of thiol–acrylate polyHIPE materials with responsive macromolecules using the highly emissive dithiomaleimide (DTM) linker is demonstrated. Functionalisation is found to be reversible upon addition of a thiol-containing compound, glutathione, resulting in switchable surface properties including fluorescence and wettability, hence broadening the scope of applications.
| Item Type: | Journal Article | ||||||||
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| Subjects: | Q Science > QD Chemistry | ||||||||
| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry Faculty of Science, Engineering and Medicine > Engineering > Engineering Faculty of Science, Engineering and Medicine > Science > Physics |
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| Library of Congress Subject Headings (LCSH): | Polymers -- Industrial applications, Emulsion polymerization, Porous materials, Imides, Macromolecules | ||||||||
| Journal or Publication Title: | Chemical Communications | ||||||||
| Publisher: | Royal Society of Chemistry | ||||||||
| ISSN: | 1359-7345 | ||||||||
| Official Date: | 11 September 2017 | ||||||||
| Dates: |
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| Volume: | 53 | ||||||||
| Number: | 70 | ||||||||
| Number of Pages: | 5 | ||||||||
| Page Range: | pp. 9789-9792 | ||||||||
| DOI: | 10.1039/C7CC03811A | ||||||||
| Status: | Peer Reviewed | ||||||||
| Publication Status: | Published | ||||||||
| Access rights to Published version: | Restricted or Subscription Access | ||||||||
| Date of first compliant deposit: | 8 September 2017 | ||||||||
| Date of first compliant Open Access: | 11 August 2018 | ||||||||
| Funder: | Monash-Warwick Alliance, National Institute for Health Research (Great Britain). Blood and Transplant Unit (NIHR BTRU), NHS Blood and Transplant (NHSBT), Leverhulme Trust (LT) | ||||||||
| Grant number: | ECF/2015-075 (LT) |
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