A chloride-bridged chain polymer: synthesis and X-ray structure of [GdCl(mu-Cl)(2)(H2O)(2)CH3CN]
UNSPECIFIED. (2003) A chloride-bridged chain polymer: synthesis and X-ray structure of [GdCl(mu-Cl)(2)(H2O)(2)CH3CN]. Inorganica Chimica Acta, 353 . pp. 276-279. ISSN 0020-1693Full text not available from this repository.
Official URL: http://dx.doi.org/10.1016/S0020-1693(03)00205-6
The title compound has been synthesised and its structure determined by X-ray diffraction. The structure comprises a single strand polymer, with five independent Gd units in the crystallographic asymmetric unit. Each gadolinium atom has eight-coordinate bicapped trigonal prismatic geometry, co-ordinated by one terminal chlorine atom, four bridging chlorine atoms, two water molecules and one acetonitrile. Linkage to neighbouring metal centres is by double halogen bridges. The mean co-ordination distances are: Gd-Cl 2.822 (bridging) and 2.676 Angstrom (terminal), Gd-O, 2.362 and Gd-N, 2.538 Angstrom. (C) 2003 Elsevier B.V. All rights reserved.
|Item Type:||Journal Article|
|Subjects:||Q Science > QD Chemistry|
|Journal or Publication Title:||Inorganica Chimica Acta|
|Publisher:||ELSEVIER SCIENCE SA|
|Date:||8 September 2003|
|Number of Pages:||4|
|Page Range:||pp. 276-279|
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