Application of amplitude-modulated radiofrequency fields to the magic-angle spinning NMR of spin-7/2 nuclei
UNSPECIFIED. (2003) Application of amplitude-modulated radiofrequency fields to the magic-angle spinning NMR of spin-7/2 nuclei. JOURNAL OF MAGNETIC RESONANCE, 163 (2). pp. 310-317. ISSN 1090-7807Full text not available from this repository.
Official URL: http://dx.doi.org/10.1016/S1090-7807(03)00159-9
We report pulse sequences for the sensitivity enhancement of magic-angle spinning and multiple-quantum magic-angle spinning spectra of spin-(7)/(2) systems. Sensitivity enhancement is obtained with the use of fast amplitude-modulated (FAM) radiofrequency pulses. In one-dimensional magic-angle spinning experiments, signal enhancement of 3 is obtained by a FAM pulse followed by a soft 90 pulse. In two-dimensional multiple-quantum magic-angle spinning experiments, FAM pulses are used for both the excitation of multiple-quantum coherences and for their conversion into observable single-quantum coherences. The observed signal enhancements are 2.2 in 3Q experiments, 3.1 in 5Q experiments, and 4.1 in 7Q experiments, compared to the conventional two-pulse scheme. The pulse schemes are demonstrated on the Sc-45 NMR of Sc-2(SO4)(3) (.) 5H(2)O and the La-139 NMR of LaAlO3. We also demonstrate the generation of FAM pulses by double-frequency irradiation. (C) 2003 Published by Elsevier Science (USA).
|Item Type:||Journal Article|
|Subjects:||Q Science > QD Chemistry
Q Science > QC Physics
|Journal or Publication Title:||JOURNAL OF MAGNETIC RESONANCE|
|Publisher:||ACADEMIC PRESS INC ELSEVIER SCIENCE|
|Number of Pages:||8|
|Page Range:||pp. 310-317|
Actions (login required)