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Cellulose hydrogenolysis with the use of the catalysts supported on hypercrosslinked polystyrene
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Sulman, E. M., Matveeva, V. G., Manaenkov, O. V., Filatova, A. E., Kislitza, O. V., Doluda, V. Yu., Rebrov, Evgeny V., Sidorov, A. I. and Shimanskaya, E. I. (2016) Cellulose hydrogenolysis with the use of the catalysts supported on hypercrosslinked polystyrene. In: 4th International Conference on Fundamental and Applied Sciences, Kuala Lumpur, Malaysia, 15–17 Aug 2016. Published in: AIP Conference Proceedings, 1787 (1). 030004. ISBN 9780735414518. ISSN 0094-243X. doi:10.1063/1.4968069
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Official URL: http://dx.doi.org/10.1063/1.4968069
Abstract
The study presents the results of cellulose hydrolytic hydrogenation process in subcritical water in the presence of Ru-containing catalysts based on hypercrosslinked polystyrene (HPS) MN-270 and its functionalized analogues: NH2-HPS (MN-100) and SO3H-HPS (MN-500). It was shown that the replacement of the traditional support (carbon) by HPS increases the yield of the main cellulose conversion products – polyols – important intermediates for the chemical industry. The catalysts were characterized using transmission electron microscopy (TEM), high resolution TEM, and porosity measurements. Catalytic studies demonstrated that the catalyst containing 1.0% Ru and based on MN-270 is the most active. The total yield of sorbitol and mannitol was 50% on the average at 85% cellulose conversion.
| Item Type: | Conference Item (Paper) | ||||||
|---|---|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry | ||||||
| Divisions: | Faculty of Science > Engineering | ||||||
| Library of Congress Subject Headings (LCSH): | Hydrogenolysis, Cellulose, Catalysts, Polystyrene | ||||||
| Journal or Publication Title: | AIP Conference Proceedings | ||||||
| Publisher: | American Institute of Physics | ||||||
| ISBN: | 9780735414518 | ||||||
| ISSN: | 0094-243X | ||||||
| Official Date: | 2016 | ||||||
| Dates: |
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| Date of first compliant deposit: | 3 November 2017 | ||||||
| Volume: | 1787 | ||||||
| Number: | 1 | ||||||
| Page Range: | 030004 | ||||||
| DOI: | 10.1063/1.4968069 | ||||||
| Status: | Peer Reviewed | ||||||
| Publication Status: | Published | ||||||
| Access rights to Published version: | Restricted or Subscription Access | ||||||
| Funder: | Rossiĭskiĭ nauchnyĭ fond [Russian Science Foundation] | ||||||
| Grant number: | Grant 15-13-20015 | ||||||
| Conference Paper Type: | Paper | ||||||
| Title of Event: | 4th International Conference on Fundamental and Applied Sciences | ||||||
| Type of Event: | Conference | ||||||
| Location of Event: | Kuala Lumpur, Malaysia | ||||||
| Date(s) of Event: | 15–17 Aug 2016 |
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