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Cellulose hydrogenolysis with the use of the catalysts supported on hypercrosslinked polystyrene

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Sulman, E. M., Matveeva, V. G., Manaenkov, O. V., Filatova, A. E., Kislitza, O. V., Doluda, V. Yu., Rebrov, Evgeny V., Sidorov, A. I. and Shimanskaya, E. I. (2016) Cellulose hydrogenolysis with the use of the catalysts supported on hypercrosslinked polystyrene. In: 4th International Conference on Fundamental and Applied Sciences, Kuala Lumpur, Malaysia, 15–17 Aug 2016. Published in: AIP Conference Proceedings, 1787 (1). 030004. ISBN 9780735414518. doi:10.1063/1.4968069 ISSN 0094-243X.

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Official URL: http://dx.doi.org/10.1063/1.4968069

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Abstract

The study presents the results of cellulose hydrolytic hydrogenation process in subcritical water in the presence of Ru-containing catalysts based on hypercrosslinked polystyrene (HPS) MN-270 and its functionalized analogues: NH2-HPS (MN-100) and SO3H-HPS (MN-500). It was shown that the replacement of the traditional support (carbon) by HPS increases the yield of the main cellulose conversion products – polyols – important intermediates for the chemical industry. The catalysts were characterized using transmission electron microscopy (TEM), high resolution TEM, and porosity measurements. Catalytic studies demonstrated that the catalyst containing 1.0% Ru and based on MN-270 is the most active. The total yield of sorbitol and mannitol was 50% on the average at 85% cellulose conversion.

Item Type: Conference Item (Paper)
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science, Engineering and Medicine > Engineering > Engineering
Library of Congress Subject Headings (LCSH): Hydrogenolysis, Cellulose, Catalysts, Polystyrene
Journal or Publication Title: AIP Conference Proceedings
Publisher: American Institute of Physics
ISBN: 9780735414518
ISSN: 0094-243X
Official Date: 2016
Dates:
DateEvent
2016Published
1 November 2016Accepted
Volume: 1787
Number: 1
Page Range: 030004
DOI: 10.1063/1.4968069
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access
Date of first compliant deposit: 3 November 2017
Date of first compliant Open Access: 7 November 2017
Funder: Rossiĭskiĭ nauchnyĭ fond [Russian Science Foundation]
Grant number: Grant 15-13-20015
Conference Paper Type: Paper
Title of Event: 4th International Conference on Fundamental and Applied Sciences
Type of Event: Conference
Location of Event: Kuala Lumpur, Malaysia
Date(s) of Event: 15–17 Aug 2016

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