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Synthesis and application to asymmetric allylic animation of substituted monodonor diazaphospholidine ligands
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UNSPECIFIED (2003) Synthesis and application to asymmetric allylic animation of substituted monodonor diazaphospholidine ligands. TETRAHEDRON, 59 (34). pp. 6473-6480. doi:10.1016/S0040-4020(03)01062-7 ISSN 0040-4020.
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Official URL: http://dx.doi.org/10.1016/S0040-4020(03)01062-7
Abstract
The synthesis of a series of substituted monodonor diazaphospholidine ligands is described. A regioselective lithiation on process is a key step in one of these syntheses. The compounds are designed to be incorporated into soluble polymer and other solid phase supports. Enantiomeric excesses of up to 88% were observed when these compounds were employed in palladium-catalysed asymmetric amination reactions. (C) 2003 Elsevier Ltd. All rights reserved.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | TETRAHEDRON | ||||
Publisher: | PERGAMON-ELSEVIER SCIENCE LTD | ||||
ISSN: | 0040-4020 | ||||
Official Date: | 18 August 2003 | ||||
Dates: |
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Volume: | 59 | ||||
Number: | 34 | ||||
Number of Pages: | 8 | ||||
Page Range: | pp. 6473-6480 | ||||
DOI: | 10.1016/S0040-4020(03)01062-7 | ||||
Publication Status: | Published |
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