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Synthesis and application to asymmetric allylic animation of substituted monodonor diazaphospholidine ligands
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UNSPECIFIED (2003) Synthesis and application to asymmetric allylic animation of substituted monodonor diazaphospholidine ligands. TETRAHEDRON, 59 (34). pp. 6473-6480. ISSN 0040-4020
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Official URL: http://dx.doi.org/10.1016/S0040-4020(03)01062-7
Abstract
The synthesis of a series of substituted monodonor diazaphospholidine ligands is described. A regioselective lithiation on process is a key step in one of these syntheses. The compounds are designed to be incorporated into soluble polymer and other solid phase supports. Enantiomeric excesses of up to 88% were observed when these compounds were employed in palladium-catalysed asymmetric amination reactions. (C) 2003 Elsevier Ltd. All rights reserved.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | TETRAHEDRON |
| Publisher: | PERGAMON-ELSEVIER SCIENCE LTD |
| ISSN: | 0040-4020 |
| Date: | 18 August 2003 |
| Volume: | 59 |
| Number: | 34 |
| Number of Pages: | 8 |
| Page Range: | pp. 6473-6480 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/9420 |
Data sourced from Thomson Reuters' Web of Knowledge
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