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Magnetic and structural characterisation of the layered materials AMnFe(C2S2O2)(3)
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UNSPECIFIED (2003) Magnetic and structural characterisation of the layered materials AMnFe(C2S2O2)(3). In: 8th International Conference on Molecule-Based Magnets (ICMM 2002), VALENCIA, SPAIN, OCT 05-10, 2002. Published in: POLYHEDRON, 22 (14-17). pp. 2317-2324. doi:10.1016/S0277-5387(03)00297-3 ISSN 0277-5387.
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Official URL: http://dx.doi.org/10.1016/S0277-5387(03)00297-3
Abstract
We present structural and magnetic data on the series of compounds AMn(II)Fe(III)(C2S2O2)(3) with A = N(CnH2n+1)(4) (n = 3-5) or P(C6H5)(4). The tetra-alkyl ammonium compounds are all ferromagnets with T-C = 10 K, whilst the tetraphenyl phosphonium compound is a ferrimagnet with T-N = 15 K. EXAFS spectroscopy shows that there is significant disorder in the orientation of the dithio-oxalate moiety, while high resolution X-ray powder diffraction measurements prove that the dithio-oxalate materials are structurally analogous to the layered oxalates. (C) 2003 Elsevier Science Ltd. All rights reserved.
Item Type: | Conference Item (UNSPECIFIED) | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | POLYHEDRON | ||||
Publisher: | PERGAMON-ELSEVIER SCIENCE LTD | ||||
ISSN: | 0277-5387 | ||||
Official Date: | 15 July 2003 | ||||
Dates: |
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Volume: | 22 | ||||
Number: | 14-17 | ||||
Number of Pages: | 8 | ||||
Page Range: | pp. 2317-2324 | ||||
DOI: | 10.1016/S0277-5387(03)00297-3 | ||||
Publication Status: | Published | ||||
Title of Event: | 8th International Conference on Molecule-Based Magnets (ICMM 2002) | ||||
Location of Event: | VALENCIA, SPAIN | ||||
Date(s) of Event: | OCT 05-10, 2002 |
Data sourced from Thomson Reuters' Web of Knowledge
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