Structure of oxychloride glasses by neutron and x-ray 'difference' and x-ray photoelectron spectroscopy
UNSPECIFIED (2003) Structure of oxychloride glasses by neutron and x-ray 'difference' and x-ray photoelectron spectroscopy. JOURNAL OF PHYSICS-CONDENSED MATTER, 15 (27). pp. 4679-4693. ISSN 0953-8984Full text not available from this repository.
A previous study of the binary system, [Sb2O3](x)-[ZnCl2](1-x) (Johnson et al 2003 J. Phys.: Condens. Matter 15 755-64), where nominally x = 0.25, 0.50, 0.75 and 1.00, has been extended to include Sb2O3-PbCl2. Information about the structure has been obtained from a combination of neutron and x-ray diffraction measurements, which were complemented by x-ray photoelectron spectroscopy. The data clearly show preferential bonding of oxygen to antimony and chlorine to zinc or lead in a single-phase glass with minimal change in the polyhedral structure with composition. The structure appears to be controlled by the need to avoid Sb-Cl-Sb links.
|Item Type:||Journal Article|
|Subjects:||Q Science > QC Physics|
|Journal or Publication Title:||JOURNAL OF PHYSICS-CONDENSED MATTER|
|Publisher:||IOP PUBLISHING LTD|
|Date:||16 July 2003|
|Number of Pages:||15|
|Page Range:||pp. 4679-4693|
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