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Structure of oxychloride glasses by neutron and x-ray 'difference' and x-ray photoelectron spectroscopy
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UNSPECIFIED (2003) Structure of oxychloride glasses by neutron and x-ray 'difference' and x-ray photoelectron spectroscopy. JOURNAL OF PHYSICS-CONDENSED MATTER, 15 (27). pp. 4679-4693. ISSN 0953-8984
Full text not available from this repository.Abstract
A previous study of the binary system, [Sb2O3](x)-[ZnCl2](1-x) (Johnson et al 2003 J. Phys.: Condens. Matter 15 755-64), where nominally x = 0.25, 0.50, 0.75 and 1.00, has been extended to include Sb2O3-PbCl2. Information about the structure has been obtained from a combination of neutron and x-ray diffraction measurements, which were complemented by x-ray photoelectron spectroscopy. The data clearly show preferential bonding of oxygen to antimony and chlorine to zinc or lead in a single-phase glass with minimal change in the polyhedral structure with composition. The structure appears to be controlled by the need to avoid Sb-Cl-Sb links.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QC Physics |
| Journal or Publication Title: | JOURNAL OF PHYSICS-CONDENSED MATTER |
| Publisher: | IOP PUBLISHING LTD |
| ISSN: | 0953-8984 |
| Date: | 16 July 2003 |
| Volume: | 15 |
| Number: | 27 |
| Number of Pages: | 15 |
| Page Range: | pp. 4679-4693 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/9465 |
Data sourced from Thomson Reuters' Web of Knowledge
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