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Synthesis of carbonates and related compounds from carbon dioxide via methanesulfonyl carbonates
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UNSPECIFIED. (2003) Synthesis of carbonates and related compounds from carbon dioxide via methanesulfonyl carbonates. JOURNAL OF ORGANIC CHEMISTRY, 68 (14). pp. 5439-5444. ISSN 0022-3263
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Official URL: http://dx.doi.org/10.1021/jo026753g
Abstract
Carbonate anions resulting from reaction of primary or secondary alcohols with carbon dioxide, when added to methanesulfonic anhydride in cooled acetonitrile solution, yield methanesulfonyl carbonates, a new class of synthetic intermediate. Base-mediated reaction of the methanesulfonyl carbonates with alcohols, thiols, and amines yields carbonates, thiocarbonates, and carbamates, respectively. Overall yields for the three steps vary from 19% to 42%.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | JOURNAL OF ORGANIC CHEMISTRY |
| Publisher: | AMER CHEMICAL SOC |
| ISSN: | 0022-3263 |
| Date: | 11 July 2003 |
| Volume: | 68 |
| Number: | 14 |
| Number of Pages: | 6 |
| Page Range: | pp. 5439-5444 |
| Identification Number: | 10.1021/jo026753g |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/9544 |
Data sourced from Thomson Reuters' Web of Knowledge
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