UNSPECIFIED. (2003) Chiral-at-metal organolanthanides: enantioselective aminoalkene hydroamination/cyclisation with non-cyclopentadienyls. CHEMICAL COMMUNICATIONS (14). pp. 1770-1771. ISSN 1359-7345

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Abstract

Chiral non-racemic complexes [ML{N(SiMe2H)(2)}(thf)] ( M = Y, La, H2L = salicylaldimine ligands derived from 2,2'-diamino-6,6- dimethylbiphenyl) are found not to be effective catalysts for the intramolecular hydroamination of aminoalkenes, but new amino/phenoxide ligand designs without reducible functional groups led to long-lived and enantioselective catalysts.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry
Journal or Publication Title:	CHEMICAL COMMUNICATIONS
Publisher:	ROYAL SOC CHEMISTRY
ISSN:	1359-7345
Date:	2003
Number:	14
Number of Pages:	2
Page Range:	pp. 1770-1771
Identification Number:	10.1039/b305105f
Publication Status:	Published
URI:	http://wrap.warwick.ac.uk/id/eprint/9587

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