Mechanistic aspects of copper-mediated living radical polymerization
UNSPECIFIED (2003) Mechanistic aspects of copper-mediated living radical polymerization. In: 224th National Meeting of the American-Chemical-Society, BOSTON, MASSACHUSETTS, AUG 17-22, 2002. Published in: ADVANCES IN CONTROLLED/LIVING RADICAL POLYMERIZATION, 854 pp. 148-160.Full text not available from this repository.
A series of aminomethacrylate ((dimethylamino)ethyl methacrylate, (diethylamino)ethyl methacrylate and t-butylaminoethyl methacrylate) monomers and a series of methoxy[poly(ethylene glycol)] methacrylate macromonomers of different molecular weights have been copolymerized with methyl methacrylate under free radical and transition-metal mediated conditions. Significantly greater levels of comonomer incorporation were observed under transitionmetal mediated conditions for all comonomers. This is attributed to complex formation between comonomer and catalyst, which is presumed to affect the reactivity of the monomer double bond.
|Item Type:||Conference Item (UNSPECIFIED)|
|Subjects:||Q Science > QD Chemistry|
|Series Name:||ACS SYMPOSIUM SERIES|
|Journal or Publication Title:||ADVANCES IN CONTROLLED/LIVING RADICAL POLYMERIZATION|
|Publisher:||AMER CHEMICAL SOC|
|Number of Pages:||13|
|Page Range:||pp. 148-160|
|Title of Event:||224th National Meeting of the American-Chemical-Society|
|Location of Event:||BOSTON, MASSACHUSETTS|
|Date(s) of Event:||AUG 17-22, 2002|
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